What Happens to the Effective Potential in a Hydrogen Atom for l>0 and r<r(min)?

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SUMMARY

The discussion focuses on the behavior of the effective potential in a hydrogen atom when the orbital angular momentum (l) is greater than zero and the electron radius (r) is less than the minimum radius (r(min)). It is established that r(min) is defined as l(l+1)a, where 'a' is the Bohr radius. The effective potential does not immediately become positive after crossing the minimum; rather, it includes a centrifugal barrier that contributes to an effective repulsion. The relationship between potential and force is clarified, emphasizing that the force remains attractive despite the potential's sign change.

PREREQUISITES
  • Understanding of quantum mechanics concepts, particularly the hydrogen atom model.
  • Familiarity with effective potential and its mathematical representation.
  • Knowledge of angular momentum in quantum systems.
  • Basic principles of forces and potentials in physics.
NEXT STEPS
  • Study the derivation of effective potential in quantum mechanics.
  • Explore the concept of centrifugal force in the context of angular momentum.
  • Learn about the implications of crossing potential minima in quantum systems.
  • Investigate the relationship between potential energy and force in classical and quantum mechanics.
USEFUL FOR

Students and professionals in physics, particularly those studying quantum mechanics, atomic structure, and angular momentum dynamics. This discussion is beneficial for anyone seeking to deepen their understanding of effective potential in hydrogen atoms.

alfredbester
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Basic SE, Hydrogen atom I'm given the basicc equation for the effective potential I've worked out the bohr radius (a)

Q. Describe what happens to the effective potential for orbital angular momentum l>0 and electron radius r < r(min)

r(min) = l(l+1)a

I'm thinking that the effective potential will become positive which would indicate that the electron will repel but am having a hard time seeing how positives and negatives can repel.

My answer (2nd year exam). Would probably be.

The effective potential will become positive which indicates a negative charge is repelled by a positive one. This is not a physically possible solution,.
 
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Hi alfred,

I think you would find it helpful to make a little sketch of the effective potential. One thing you will see is that the effective potential does not immediately become positive after the minimum is passed. In fact, you know that the sign of the potential doesn't determine whether the force is attractive or repulsive. Remember that you can always add a constant to the potential without changing the physics. Something does change, however, when you cross the minimum of the potential. Hint: how does the potential relate to the force?

Also, the effective potential includes the centrifugal barrier (the angular momentum piece) which can lead to an effective repulsion. What is the physical origin of this seeming repulsion?
 
Last edited:
Thanks, the distance derivative of the potential is the Force (F = - dU/dr) so the force is attractive since r<rmin has negative gradient.

The second part I think, as r is decreasing the velocity needs to increase to conserve angular momentum so the centrifrugal (outward) force (proportional to v-squared) increases.
 

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