I think I'll take a stab at this. I'll try to make this fun and step away from the formalities for now.
Below is a hyperlink to a map of Yellowstone National Park*.
http://yellowstone.net/maps/files/2012/06/yellowstone-map.jpg
The map is perfectly flat; you can see it on your computer monitor, after all! But, as everyone knows by now, Earth is
not flat. It is (roughly) spherical.
Is the map wrong? How can something be flat and not flat at the same time?
Clearly, the map isn't "wrong". Anyone who has navigated using a map knows that maps work very well for finding locations. Resolution comes from the idea of
local flatness. This can be made rigorous with a bit of topology, using the language of "homeomorphisms". Again, we will avoid this. The idea is fairly simple, though: if you were walking around on a sphere, then you would not be able to tell the difference between your surroundings and a plane (\mathbb{R}^2).
Generalizing, the "defining" property of a manifold is the following: if you were walking around on a manifold, then you would not be able to tell the difference between your surroundings and Euclidean space (\mathbb{R}^n).
Curvature is a little bit harder to describe, especially since there are a LOT of ways to look at it. I'll do my best.
The tangent space to a point on a manifold is something that we can define if our manifold is really nice. Intuitively, we can think of it as exactly what it sounds like: the space of vectors originating from a point on a manifold such that the vectors are tangent to the manifold. One problem for manifolds is that we cannot add vectors from different tangent spaces without extra structure. After all, if you are pushing on a box, the force you exert will not magically act on another box that is several miles from you; it acts on your box.
We can resolve this in several ways. One way, from "Riemannian geometry," is to introduce a "connection". Without going into too much detail, connection provides a way of pushing tangent vectors along a curve. Most of the time, we disguise connections as things called "covariant derivatives," which are a kind of generalization of the derivative. Curvature, vaguely speaking, is a way of measuring how much the covariant derivative doesn't act like regular derivatives, in the sense of
"equality of mixed partials."
*For non-American readers, all you need to know is that Yellowstone is a REAAALLY big park.