What is meant by Early atomic models predicted noble gas stable

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Discussion Overview

The discussion revolves around the statement regarding early atomic models predicting the stability of atoms and ions with noble gas electron arrangements. Participants explore the implications of this prediction, the context of early atomic theories, and the relationship between electron configurations and stability.

Discussion Character

  • Exploratory
  • Technical explanation
  • Conceptual clarification
  • Debate/contested

Main Points Raised

  • Michael questions whether the statement about noble gas stability refers specifically to the Niels Bohr model or if there are other considerations.
  • One participant suggests modeling the nucleus similarly to electron shells, proposing that nuclei with certain numbers of protons and neutrons might also exhibit stability, although this may not hold for larger nuclei.
  • Michael expresses that the phrase in his specification is vague and seeks clarification on its meaning.
  • Another participant clarifies that the discussion pertains solely to electron shells and notes that while noble gas arrangements were considered stable, exceptions exist, such as the formation of argon and xenon fluorides.
  • A different participant points out that knowledge of electron behavior predates the Bohr model, highlighting the significance of periodicity in ionization energies and its relation to stability.

Areas of Agreement / Disagreement

Participants express differing views on the implications of early atomic models and the stability of noble gas configurations. There is no consensus on the interpretation of the statement or the extent to which early models accurately predict stability.

Contextual Notes

Some participants note the limitations of early models in accounting for exceptions in stability, particularly regarding larger nuclei and the behavior of certain compounds.

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What is meant by "Early atomic models predicted...noble gas...stable"

Hello,
I am troubled by the following statement "Early models of atomic structure predicted that atoms and ions with noble gas electron arrangements should be stable"
Is this referring to the Niels Bohr model or am I missing out on something?

All opinions are appreciated.
Michael
 
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Do you have some context?

My guess:
You can try to model a nucleus similar to electron shells - both protons and neutrons are fermions, so they have to occupy different energy levels, similar to electrons. There, nuclei with 2, 10, 18, 36, ... electrons have closed shells, and they are very stable (high binding + ionisation energy). If you transfer that to atoms, you would expect that atoms with 2, 10, 18, ... protons and neutrons are very stable. While this is true for 2 (helium-4), it becomes wrong for larger numbers.
The reason: The nucleus is a bit different, as you have a different potential shape (no 1/r-potential, but a sharp border) and different effects from proton<->proton repulsion for large nuclei.
 


That makes sense. I found the phrase in my specification under "Atomic Structure, Fundamental particles, Candidates should know that early models of atomic structure predicted that atoms and ions with noble gas electron arrangements should be stable". Which to be hones I found quite vague.

Michael
 


I understand the question refers exclusively to electron shells, not to nuclei.

Noble gas electron arrangements stable: onyl early, because meanwhile we know argon and xenon fluorides can be produced and kept for many minutes.
 


Knowledge of electrons had to predate any electron-proton models.

In fact much was knownbefore the Bohr model and in particular the observation of periodicity in ionisation energies.

I have shown pat of the graph, a proper search will show the whole picture, but the ionisation (negative) energies of helium and Neon are about five times as great as for lithium and sodium.

So it stand to reason that the greater the I energy the less likely that the electron will be removed leading to the conclusion that the elements with greatest I energies will be the most stable.
 

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Thank you all. I'm glad I asked.

Michael
 

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