What is second oxide in a glass system?

In summary, the conversation discusses the composition and classification of a specific type of glass, [(TeO2)70(B2O3)30]1-x(CuO)x. The question is raised about whether this is a binary oxide glass, and the definition of second oxide is clarified. It is determined that CuO is the second oxide for this glass, but if x is very small it can be considered a doped binary glass. The speaker also mentions their experience with making and observing the optical properties of this glass, with x ranging from 0.1 to 0.3. Ultimately, it is concluded that the Te and B oxides are the binary oxides and CuO acts as a network modifier.
  • #1
Donchay
10
0
is [(TeO2)70(B2O3)30]1-x(CuO)x a binary oxide glass?
What is the definition of second oxide? Is the second oxide for the above glass is CuO??
 
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  • #2
I'd rather say the second oxide it is B2O3. As long as x is very small, it would call it a doped binary oxide glass or the like. However if x is of the order of 1, then it is a ternary glass.
 
  • #3
I've been making glass and observe their optical properties from range of x=0.1 to x=0.3. So that would make CuO the second oxide, and thus binary glass?
 
  • #4
I would say that the Te and B oxides are the binary oxides as they would be the network formers; Cu most likely acts as a network modifier; that is, it exists to perturb the ratio of O to Te and B without "participating" in the covalent bond network.

Claude.
 

What is second oxide in a glass system?

The second oxide in a glass system refers to the second most dominant oxide in a glass composition, after the primary oxide. It plays a crucial role in determining the properties and characteristics of the glass.

What are the common second oxides found in glass?

Some of the most common second oxides found in glass include alumina, boron oxide, phosphorus oxide, lead oxide, and zirconia. These oxides can affect the glass's properties, such as its melting point, viscosity, and chemical resistance.

How does the second oxide affect glass properties?

The second oxide can greatly influence the physical, chemical, and optical properties of glass. For example, alumina can increase the glass's strength and hardness, while boron oxide can lower its melting point and improve its thermal shock resistance.

Can different combinations of second oxides create different types of glass?

Yes, the combination and proportion of second oxides in a glass composition can create different types of glass with unique properties. For instance, adding lead oxide to a silica-based glass can produce a heavy, dense glass suitable for making crystal products.

How do scientists determine the optimal amount of second oxide in a glass composition?

Scientists use various techniques, such as phase diagrams and computer simulations, to determine the optimal amount of second oxide in a glass composition. They also conduct experiments to analyze the effects of different oxide ratios on the glass's properties before finalizing the composition.

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