What is the Behavior of Particle Distribution Near Maximum in Thermal Physics?

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SUMMARY

The discussion focuses on the behavior of particle distribution near the maximum in thermal physics, specifically analyzing a system where particles are distributed between two equal volumes. It establishes that when there are n = (Na/2) + k particles in one partition, the distribution approaches a Gaussian form as k approaches zero. The key to solving the problem lies in utilizing the partition function for an ideal gas, which can be derived through integration. The resulting quadratic form from the product of the two partition functions confirms the Gaussian behavior near the maximum distribution.

PREREQUISITES
  • Understanding of ideal gas behavior and properties
  • Familiarity with partition functions in statistical mechanics
  • Knowledge of Gaussian distribution and its mathematical properties
  • Basic concepts of thermal physics and statistical distributions
NEXT STEPS
  • Study the derivation of the partition function for ideal gases
  • Learn about the application of Gaussian distributions in statistical mechanics
  • Explore the binomial distribution and its relation to particle distributions
  • Investigate the implications of particle statistics in thermal equilibrium
USEFUL FOR

This discussion is beneficial for students and researchers in thermal physics, particularly those exploring statistical mechanics and particle distribution behaviors in ideal gas systems.

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Homework Statement


There is a box of volume V that is divided into two equal parts: Left side = V/2 = right side.
The problem is:
Assume that there are n = (Na/2) + k particles in the left hand partition where k is a small integer ( k << Na). Show that the behavior near the maximum where n = Na/2 is gaussian (i.e., quadratic in k).



Homework Equations


Na = 6.022x1023

This is what I don't know. I don't know if I'm supposed to use the binomial distribution or the gaussian(normal) distribution.

I'm in Thermal Physics because statistics was not a pre-req but we're using a lot of statistics and I've never had a course on it. So if anyone could help point me in the right direction of how to go about showing this, I would greatly appreciate it.
 
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I feel like information is missing. I'm assuming that the particles in the box are ideal gas particles? If so I think you need to find the partition function. To give you a hint the partition function for an ideal gas is found using an integral (wikipedia it and hopefully you might have seen it before). If there are (Na/2)+k in the left hand part then there are (Na/2)-k in the right hand part. Each partition function is independent so if you found the partition function for either side, to get the total partition function for the whole box you could just multiply the two together. I haven't worked through it but I can see ((Na/2)+k)((Na/2)-k) is going to give you a quadratic.
 

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