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deepalakshmi
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I have seen the structures like X3 (HITP)2 (X = Cr, Mn, Fe, Co, Rh, Os, Ir). Can I replace X with Mg? Will it be stable?
What is the charge for Hexaminotriphenylene?
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SUMMARY
The discussion centers on the stability of Hexaminotriphenylene (HITP) metal-organic frameworks (MOFs) when substituting transition metals with magnesium (Mg). Participants note that while metals like chromium (Cr), manganese (Mn), iron (Fe), cobalt (Co), rhodium (Rh), osmium (Os), and iridium (Ir) are transition elements, magnesium lacks this characteristic, raising concerns about the stability of the resulting compound. The consensus indicates that the square planar configuration typical of HITP MOFs is not compatible with magnesium, further questioning its viability as a substitute.
PREREQUISITES- Understanding of metal-organic frameworks (MOFs)
- Knowledge of transition metals and their properties
- Familiarity with coordination chemistry
- Basic concepts of molecular stability and structural configurations
- Research the properties of transition metals in coordination complexes
- Explore the structural characteristics of square planar coordination
- Investigate the stability of magnesium compounds in MOF applications
- Learn about the synthesis and applications of HITP-based MOFs
Chemists, materials scientists, and researchers interested in metal-organic frameworks and the implications of using non-transition metals in MOF synthesis.
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