What is the connection between mathematics and Hess's Law?

  • Thread starter Thread starter behemuthxero
  • Start date Start date
  • Tags Tags
    Law Mathematics
Click For Summary
SUMMARY

The discussion centers on the relationship between mathematics and Hess's Law, specifically how enthalpy change, a state function, can be analyzed using mathematical techniques. Participants noted that Hess's Law allows for the manipulation of chemical equations, similar to matrix operations, to determine overall enthalpy changes. The conversation highlighted the importance of integrals in expressing enthalpy and suggested that further exploration of physical chemistry texts, such as Atkins' and Moore's works, could provide deeper insights into the mathematical processes involved.

PREREQUISITES
  • Understanding of Hess's Law and its implications in thermodynamics
  • Basic knowledge of integrals and their applications in calculus
  • Familiarity with state functions in chemistry
  • Experience with manipulating chemical equations
NEXT STEPS
  • Research the mathematical foundations of Hess's Law in physical chemistry
  • Study integrals and their applications in thermodynamic equations
  • Explore matrix operations and their relevance to chemical equation manipulation
  • Read Atkins' "Physical Chemistry" and Moore's "Physical Chemistry" for advanced concepts
USEFUL FOR

Chemistry students, educators, and anyone interested in the intersection of mathematics and thermodynamics, particularly in the context of Hess's Law and enthalpy changes.

behemuthxero
Messages
1
Reaction score
0
In my chemistry class today we began covering the idea of Hess's law. That is, Enthalpy change is a state function that is independent of the path taken. We worked some example problems using several intermediate chemical equations to arrive at a system that expressed the overall enthalpy change. During these examples the equations were manipulated akin to matrix style mathematics. I was wondering if there is some connection and if so what is its process. I learned that enthalpy is a state function and thus can be express as an integral. My knowledge of Integrals is limited, we just started talking about them in Calculus last week. However, I was wondering if there was any link or established mathematical process which can be used to work problems using Hess's law. This question is more out of personal interest than a class requirement, I simply love making connections between mathematics an other fields of science.

Also, I was unsure if this should be posted in the mathematics forum or not. Apologies in advance if this post is misplaced.
 
Chemistry news on Phys.org
Obviously there are mathematical techniques of the kind you mention used in connection with Hess law. Maybe a book on physical chemistry or on thermodynamics might be interesting to you, e.g. Atkins, Physical Chemsitry, or Moore, Physical Chemsitry.
 

Similar threads

  • · Replies 3 ·
Replies
3
Views
4K
  • · Replies 2 ·
Replies
2
Views
2K
  • · Replies 24 ·
Replies
24
Views
2K
Replies
12
Views
3K
Replies
9
Views
3K
  • · Replies 2 ·
Replies
2
Views
3K
  • · Replies 2 ·
Replies
2
Views
2K
  • · Replies 6 ·
Replies
6
Views
3K
Replies
8
Views
3K
  • · Replies 1 ·
Replies
1
Views
2K