What is the impact of synergy in erosion-corrosion and how can it be measured?

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Discussion Overview

The discussion centers on the impact of synergy in erosion-corrosion, specifically how the interaction between electro-chemical corrosion and mechanical erosion contributes to material loss. Participants explore methods to quantify this synergy effect and evaluate erosion quantitatively based on known parameters.

Discussion Character

  • Exploratory
  • Technical explanation
  • Debate/contested
  • Mathematical reasoning

Main Points Raised

  • One participant notes that erosion-corrosion involves weight loss from both electro-chemical corrosion and mechanical impingement, with a third synergy effect from their interaction.
  • Another participant questions the proportion of weight loss attributable to the synergy effect and requests references for a university report.
  • A different participant asserts that erosion typically accounts for the majority of mass loss, while corrosion primarily converts metal to oxide, which may also dissolve under certain conditions.
  • This same participant discusses the role of oxide layers in corrosion resistance, suggesting that a uniform and thick oxide layer can passivate the metal and slow further corrosion.
  • One participant expresses a desire for a quantitative method to evaluate material loss due to erosion, similar to the application of Faraday's law for electrochemical corrosion.

Areas of Agreement / Disagreement

Participants express differing views on the contributions of erosion and corrosion to material loss, and there is no consensus on how to quantify the synergy effect or erosion itself. The discussion remains unresolved regarding the specific proportions and methods for measurement.

Contextual Notes

Participants have not provided specific assumptions or definitions regarding the synergy effect, nor have they resolved the mathematical steps necessary for quantifying erosion. The discussion lacks a clear framework for measurement.

bill nye scienceguy!
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In the condition of erosion-corrosion there is weight loss from the material by electro-chemical corrosion, impingement attack from the slurry and a third 'synergy' effect coming from the interaction of the other two effects.

My question is: what proportion of the weight loss tends to come from the synergy effect? If possible can you include a reference? I need to use this for a university report.
 
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In addition to this question, how can you make a quantitative evaluation wrt erosion if the velocity and particulate concentration of the impinging slurry are known?
 
Well, erosion results in the majority of mass loss. Corrosion for the most part involves a conversion of metal to an oxide usually. Of course, corrosion could involve some amount of dissolution (of the base metal or oxide), as opposed to the erosion or wearing of the oxide.

Oxides can be converted to oxyhydroxides or hydoxides which are more soluble.

For corrosion resistant material, there is a certain level of oxide, such that the oxide 'passivates' the metal. The oxide may prevent additional oxidation (corrosion) from occurring, or it may only slow the diffusion of oxygen to the metal-oxide interface. That usually requires some thickness of oxide and little or no porosity or cracking in the oxide layer. It also means that the oxide is more or less chemically uniform, e.g. Al2O3.
 
All this is true, however it doesn't really answer my question. I suppose what I'm really looking for is a way to quantify material loss due to the erosion process, equivalent to the Faraday's law method for calculating material loss due to electrochemical corrosion.
 

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