What is the relationship between intermolecular distance and pressure?

Click For Summary

Homework Help Overview

The discussion revolves around the relationship between intermolecular distance and pressure, specifically in the context of a problem that asks how to adjust pressure to double the separation between molecules while keeping temperature constant.

Discussion Character

  • Exploratory, Conceptual clarification, Assumption checking

Approaches and Questions Raised

  • Participants explore the connection between intermolecular distance and volume, and subsequently pressure. There is a suggestion to consider the relationship between average interparticle spacing and gas density. One participant introduces a formula related to molar volume and intermolecular distance, questioning its appropriateness for the problem.

Discussion Status

The discussion is active with various approaches being considered. Participants are questioning assumptions and exploring different relationships, but no consensus has been reached on a specific method or solution.

Contextual Notes

Participants are navigating the implications of keeping temperature fixed while altering pressure and intermolecular distance. There is mention of a specific formula that may or may not be applicable, indicating a need for further exploration of its relevance.

Amith2006
Messages
416
Reaction score
2
4)Sir,
Please give a hint to solve the following problem.
# In order to double the separation between the molecules (keeping the temperature fixed), how many times the initial pressure should the final pressure be made?
How do you relate intermolecular distance and pressure?
 
Physics news on Phys.org
I am guessing you need to relate intermolecular distance to volume first, then to pressure.
 
Sensou has the right idea. The average interparticle spacing will clearly be related to the density of the gas. You need to figure out the relationship between the two.
 
Sir,
When I searched the net, I came across the Lennard Jones plot of Energy verses intermolecular distance. In that it has been deduced that,
Molar volume = (Nr^3)/C
where N is Avogadro Number, r is intermolecular distance and C is a number which is dependent on the lattice coordination number. Will it be appropriate to use this expression? The symbol ^ represents power.
 

Similar threads

  • · Replies 2 ·
Replies
2
Views
3K
  • · Replies 4 ·
Replies
4
Views
2K
  • · Replies 6 ·
Replies
6
Views
2K
  • · Replies 9 ·
Replies
9
Views
3K
  • · Replies 6 ·
Replies
6
Views
2K
  • · Replies 1 ·
Replies
1
Views
2K
  • · Replies 1 ·
Replies
1
Views
2K
  • · Replies 6 ·
Replies
6
Views
2K
Replies
4
Views
3K
  • · Replies 7 ·
Replies
7
Views
2K