What Is the White Layer on Water?

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SUMMARY

The white layer observed on boiled water is primarily due to the presence of calcium bicarbonate, which transforms into calcium carbonate (limescale) when heated. This reaction occurs as follows: Ca(HCO3)2(aq) → CO2(g) + H2O(l) + CaCO3(s). Despite the use of a sand filter, the hardness of the water remains, leading to the formation of this layer. While the water contains beneficial minerals, it may require more soap for cleaning and could necessitate kettle replacements over time.

PREREQUISITES
  • Understanding of water chemistry, specifically calcium bicarbonate and calcium carbonate reactions.
  • Knowledge of water filtration systems, including sand filters.
  • Familiarity with the concept of water hardness and its implications.
  • Basic principles of heating and phase changes in liquids.
NEXT STEPS
  • Research methods to reduce water hardness, such as ion exchange or reverse osmosis.
  • Learn about the effects of limescale on household appliances and how to mitigate them.
  • Explore the benefits and drawbacks of different water filtration systems.
  • Investigate the chemistry of calcium compounds in water treatment processes.
USEFUL FOR

This discussion is beneficial for homeowners experiencing water quality issues, water treatment professionals, and anyone interested in the chemistry of water and its effects on household appliances.

mathsTKK
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I met a customer who face a problem in the water quality in the house. The water supply is clean and clear but when it is boiled or cooked, a white oily layer floats on top of the water. When the water is left cooled, the white layer hardens and sticks on the wall of the pot and container. The customer claims that a sand filter has been used to filter the water but the white layer still appear. Currently, I predict that's actually a layer of oil and I can use a paper layer filter to remove the oil. However, I wonder whether that's really oil layer or something else. Can someone tell me what's actually the white layer in the water? and what's the solution to the problem?

Thank you very much^^
 
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Thank you russ_watters^^ But can I ask why the white layer only appear when the water is heated? I still don't understand why this situation occurs...

Anyway, thank you once again and I hope for more replies soon^^
 
In solution it's Calcium bicarbonate, when you heat it the reaction forms calcium carbonate (limescale)
Ca(HCO3)2(aq) → CO2(g) + H2O(l) + CaCO3(s)

It means your water tastes nice and will have lots of useful minerals in it - at the cost of using a bit more soap and needing a new kettle every few years.
 

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