What particles have fixed weak isospin and T3?

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Gene Naden
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Wikipedia quotes weak isospin values for some particles and not for others. Why? Is the concept of weak isospin as an observable quantity not meaningful for, for example, pions?
 
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Wikipedia article on weak isospin seems to say that in some cases it is not conserved due to interaction with the Higgs field. What would be an example of a particle reaction where this is true?
 
Still wondering what is the reaction
 
Wikipedia gives a value for the weak isospin of left-handed electrons, even though they have mass. But not for pions. So when does a particle have a definite value for T and T3 and when does it not. Thanks.