Why acetaldehyde has a higher boiling point than ethylamine?

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SUMMARY

Acetaldehyde has a higher boiling point (68ºF) than ethylamine (62ºF) despite ethylamine's ability to form hydrogen bonds. The discussion highlights that hydrogen bonding is not the sole determinant of boiling points; other intermolecular forces also play a significant role. Ethylamine can effectively hydrogen bond with itself due to its lone pair on nitrogen and two amine hydrogens, but this does not compensate for the overall molecular interactions present in acetaldehyde.

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Ethylamine has 2 hydrogen bonds, Acethaldehyde has no one, so why the second has a higher boiling point?
 
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Is hydrogen bonding the only intermolecular force of consequence in this situation?

How effectively can ethylamine hydrogen bond with itself? It has a lone pair on the nitrogen to serve as an H-bond acceptor, and has two amine hydrogens that can be donated.

How large of a difference is there between the two boiling points?
 
The boiling points are very close:
Acetaldehyde 68ºF
Ethylamine: 62ºF
 

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