Why Diamond is a Poor Conductor & Graphite a Good Conductor

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Discussion Overview

The discussion centers on the electrical conductivity of diamond and graphite, exploring the structural differences between the two forms of carbon and their implications for conductivity. The scope includes conceptual understanding and technical explanations related to material properties.

Discussion Character

  • Conceptual clarification
  • Technical explanation

Main Points Raised

  • One participant suggests that diamond is a good insulator and attributes the difference in conductivity to the structural arrangement of carbon atoms in diamond (tetrahedral) versus graphite (flat groupings).
  • Another participant prompts a closer examination of the covalent bonds in both diamond and graphite, implying that this analysis could lead to deductions about their conductivity.
  • A hint is provided regarding the role of delocalized pi bonds in graphite, which may contribute to its conductivity.
  • A later reply reiterates the structural differences, noting that diamond has four bonds with no free electrons, while graphite has three bonds and a free electron that allows electric current to flow.

Areas of Agreement / Disagreement

Participants express differing views on the reasons behind the conductivity differences, with some focusing on structural aspects and others hinting at the role of electron delocalization. The discussion does not reach a consensus on the underlying mechanisms.

Contextual Notes

The discussion lacks detailed exploration of the implications of covalent bonding and delocalization on conductivity, and assumptions regarding the definitions of conductivity and bonding types are not explicitly stated.

arabianchick
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Why is diamond a poor conductor of an electric current and graphite a good conductor?

all i can come up with is that diamond is a good insulator and that the fundamental difference between graphite and diamond being that graphite molecules are flat groupings of carbon atoms while diamond molecules are tetrahedral (pyramid-shaped) groupings of carbon atoms.

can someone tell me if this is anywhere close? and help me on a bit..
 
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look carefully at the structure of both diamond and graphite. find out how many covalent bonds are there for each carbon atom in both diamond and graphite.

what can you deduce?
 
hint: delocalized pi bonds
 
arabianchick said:
Why is diamond a poor conductor of an electric current and graphite a good conductor?

all i can come up with is that diamond is a good insulator and that the fundamental difference between graphite and diamond being that graphite molecules are flat groupings of carbon atoms while diamond molecules are tetrahedral (pyramid-shaped) groupings of carbon atoms.

can someone tell me if this is anywhere close? and help me on a bit..

Graphite and diamond are both made from carbon, which has 4 electrons in it's outer shell. Diamond has four bonds, meaning there are no free electrons. Graphite has three bonds giving it a free electron which alows the current of electricity to flow. Hope this helps.
 

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