Why does glucose heated with HI produce n-hexane?

  • Thread starter Thread starter erisedk
  • Start date Start date
  • Tags Tags
    Glucose Structure
Join the discussion
Registration is free. Ask a follow-up in this thread, or start your own.
2 replies · 2K views
erisedk
Messages
372
Reaction score
7
Why does glucose on prolonged heating with HI give n-hexane?
What mechanism/reaction type is this? All I knew till now was that alcohols would give halogen substituted products with hydrogen halides.
 
Chemistry news on Phys.org
It's a reduction with hydroiodic acid being oxidized to iodate. Btw the same reaction is used in the synthesis of methamphetamine in beeaking bad.
 
Is it a common mechanism in introductory organic chemistry?