Why Does Temperature Remain Constant in Adiabatic Free Expansion?

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SUMMARY

The discussion centers on the phenomenon of temperature remaining constant during adiabatic free expansion of an ideal gas. When an ideal gas expands into a vacuum without heat exchange, the average kinetic energy of the gas molecules does not change, resulting in no change in temperature. The relevant equations, such as (T1)(V1)^(y-1)=(T2)(V2)^(y-1) and (P1)(V1)^y=(P2)(V2)^y, are applicable under quasi-static conditions, but do not apply in free expansion scenarios. The conclusion is that in free expansion, despite the volume doubling, the temperature remains constant due to the lack of work done by the gas.

PREREQUISITES
  • Understanding of ideal gas laws, specifically PV=nRT
  • Familiarity with adiabatic processes and their equations
  • Knowledge of kinetic theory of gases
  • Concept of quasi-static processes in thermodynamics
NEXT STEPS
  • Study the implications of free expansion in thermodynamics
  • Learn about quasi-static versus non-quasi-static processes
  • Explore the kinetic theory of gases in more detail
  • Investigate real gas behavior compared to ideal gas assumptions
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Students studying thermodynamics, physics educators, and anyone seeking to understand the principles of gas behavior during adiabatic processes.

Scintillation
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Homework Statement


We start with an ideal gas confined to half a container. Then, without heat flow, the gas flows into the other half as the partition is punctured. Find the new temperature after the expansion.


Homework Equations


Since there is no heat flow, I assume the process is adiabatic.

Relevant equations are:
(T1)(V1)^(y-1)=(T2)(V2)^Y-1

(P1)(V1)^y=(P2)(V2)^y

The Attempt at a Solution


Using my first equation, with T1= To, and V2=2V1, my final Temperature should be To/(2^y-1).

Except, my solution key states that there is NO change in temperature. Using the equation 1/2m(vrms)^2=3/2kt, since the velocity of each individual particle has not changed, then the temperature has not changed either.

But then what does my value of To/(2^y-1) mean? I always have trouble with these equations for adiabatic expansion/pressure. Another question I had (I can discuss this in more information if needed) is I was given the original volume, original and final pressure, as well as the original and final temperatures, and asked to find the final volume. I understand I could have used PV=nRT, but I tried using (P1)(V1)^y=(P2)(V2)^y to see if it would be the same. It was not the same, unfortunately, but I don't understand why. Can anyone help clarify either of these problems?
 
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Scintillation said:
Relevant equations are:
(T1)(V1)^(y-1)=(T2)(V2)^Y-1

(P1)(V1)^y=(P2)(V2)^y

These equations are derived assuming that the adiabatic process is slow (quasi-static). For a slow adiabatic expansion, the gas does work as it expands and the gas cools. But if the gas expands freely into a vacuum, the gas doesn't do any work and the only effect is for the molecules to spread apart. For an ideal gas where there is no interaction between the molecules (other than collision forces) the spreading out does not change the average speed of the molecules.
 

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