Why Doesn't Aluminium Corrode?

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Discussion Overview

The discussion centers around the corrosion resistance of aluminum, specifically focusing on the formation of aluminum oxide and its properties. Participants explore the reactions of aluminum with air and heat, as well as the terminology surrounding aluminum oxide, including its relationship to corundum.

Discussion Character

  • Exploratory
  • Technical explanation
  • Conceptual clarification
  • Debate/contested

Main Points Raised

  • Some participants propose that aluminum reacts with oxygen in the air to form a protective layer of aluminum oxide, which they refer to as corindone.
  • Others question the effectiveness of this oxide layer in protecting aluminum from heat and its potential reactions with carbon dioxide.
  • There is a discussion about the stability of aluminum oxide, with some noting that it is amphoteric and does not react significantly with CO2.
  • Participants express confusion over the terminology, particularly the relationship between corindone and corundum, with some suggesting they may be the same substance.
  • A later reply clarifies that corundum is a crystalline form of aluminum oxide, while the oxide layer on aluminum may not be crystalline.

Areas of Agreement / Disagreement

Participants express varying levels of understanding regarding the properties of aluminum oxide and its reactions. There is no consensus on the terminology or the implications of aluminum oxide's stability and reactivity.

Contextual Notes

Some participants exhibit uncertainty about the chemical behavior of aluminum oxide, particularly in relation to heat and carbon dioxide. There are also discrepancies in the understanding of the physical state of aluminum oxide.

Who May Find This Useful

This discussion may be useful for students studying chemistry or materials science, particularly those interested in the properties of metals and their oxides.

Jadaav
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Hi guys,

I wanted to know why does Aluminium not corrode and why does it not form a carbonate when heat is applied to it?
 
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It reacts immediately with air oxygen as soon as it comes in contact wit air, forming a very resistant and protective layer of aluminium oxide (corindone).
 


lightarrow said:
It reacts immediately with air oxygen as soon as it comes in contact wit air, forming a very resistant and protective layer of aluminium oxide (corindone).

Thanks:)

That means that the corindone protects the aluminium from corrosion.

And what about its reaction with heat to form carbonate? Does the corindone also protects it from heat or ?
 


Jadaav said:
Thanks:)

That means that the corindone protects the aluminium from corrosion.

And what about its reaction with heat to form carbonate? Does the corindone also protects it from heat or ?
What exactly do you mean with "reaction with heat"?
 


ah I meant when heat is applied to it
 


well, when I searched for corindone It lead me to corundum instead, guess its the same thing ?

'Aluminium oxide is the family of inorganic compounds with the chemical formula Al2O3. It is an amphoteric oxide and is commonly referred to as alumina, corundum as well as many other names, reflecting its widespread occurrence in nature and industry. Its most significant use is in the production of aluminium metal, although it is also used as an abrasive due to its hardness and as a refractory material due to its high melting point.'

This solves my questions about the corrosion and carbonate of Aluminium.

but still has a doubt of corindone and corundum, reply please
 


Jadaav said:
ah I meant when heat is applied to it
So you mean:

Al2O3 + 3CO2 -->heat--> Al2(CO3)3 ?

If you mean that reaction it's strange because usually carbonates decomposes, with heat. E.g. :

MgCO3-->heat--> MgO + CO2

Anyway, aluminium oxide doesn't react with CO2 essentially because it's extremely stable (inert) and also because it's not very basic (it's amphoteric).
 


lightarrow said:
So you mean:

Al2O3 + 3CO2 -->heat--> Al2(CO3)3 ?

If you mean that reaction it's strange because usually carbonates decomposes, with heat. E.g. :

MgCO3-->heat--> MgO + CO2

Anyway, aluminium oxide doesn't react with CO2 essentially because it's extremely stable (inert) and also because it's not very basic (it's amphoteric).

Why you react Aluminium oxide with Carbon dioxide?
 


I have now understood it completely:)

Aluminium oxide is a non-reactive gas and can only react as an acid or base.:)

that's going to help me very much for my exam:D

thanks very much mate;)
 
  • #10


Jadaav said:
well, when I searched for corindone It lead me to corundum instead, guess its the same thing ?
Yes, forgive my mistake, I thought in english was the same as in italian...
 
  • #11


Jadaav said:
I have now understood it completely:)

Aluminium oxide is a non-reactive gas and can only react as an acid or base.

If you are calling aluminum oxide a gas, you have still a lot to understand.

Note that corundum is a name for crystalline aluminum oxide. I doubt oxide layer on the metal surface is crystalline, microcrystalline at best.
 
Last edited:
  • #12


lightarrow said:
Yes, forgive my mistake, I thought in english was the same as in italian...

Nevermind;),

Didn't expect to have this question in my exam, but glad that I could answer.

I didn't put aluminium oxide in the exam, hope fully.

It was only asked to explain briefly:D
 
  • #13


Borek said:
If you are calling aluminum oxide a gas, you have still a lot to understand.

Note that corundum is a name for crystalline aluminum oxide. I doubt oxide layer on the metal surface is crystalline, microcrystalline at best.

I know, I'm still at a low level though.
 
  • #14


Borek said:
Note that corundum is a name for crystalline aluminum oxide.
Correct.
I doubt oxide layer on the metal surface is crystalline, microcrystalline at best.
Yes, I agree with you.
 

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