Why is CN stable in low pressure but unstable otherwise?

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Discussion Overview

The discussion centers around the stability of the CN molecule under varying pressure conditions, particularly its stability in low-pressure environments such as those found in comets compared to its instability under normal terrestrial conditions. The conversation explores the implications of CN being a free radical and the effects of pressure on its stability.

Discussion Character

  • Exploratory
  • Technical explanation
  • Conceptual clarification
  • Debate/contested

Main Points Raised

  • Some participants note that CN is a free radical due to having one unpaired valence electron.
  • There is a suggestion that the instability of CN at higher pressures may be related to increased collision frequencies, as indicated by kinetic theory of gases.
  • Participants discuss the reactivity of atoms with unpaired electrons, implying that this reactivity contributes to the instability of CN under normal conditions.
  • One participant prompts others to draw connections between the reactivity of free radicals and the observations made about CN's stability in different pressure environments.

Areas of Agreement / Disagreement

Participants generally agree that CN is a free radical and that its stability is influenced by pressure, but the discussion remains unresolved regarding the specific mechanisms that lead to its instability at higher pressures.

Contextual Notes

The discussion does not fully explore the assumptions related to the definitions of stability and reactivity, nor does it clarify the mathematical or theoretical frameworks that underpin the claims about pressure effects on free radicals.

zachem62
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Here's the question:
The CN molecule has been observed spectroscopically in comets where pressure has been estimated to be as low as 10–10 mm Hg. Draw a Lewis structure for CN. Suggest an explanation as to why this species can persist in a comet but is unstable under normal terrestrial conditions.

The only progress I could make was to realize that CN is a free radical since it has 1 unpaired valence electron. And if I understand the question correctly, CN is stable under conditions of extremely low pressure but unstable at normal conditions of higher pressure, and its asking why this is, and I'm kind of clueless. Please help! Thanks.
 
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zachem62 said:
CN is a free radical since it has 1 unpaired valence electron
... and, what happens to free radicals at higher pressures? Think about collision frequencies, kinetic theory of gases, mean free path ...
 
Bystander said:
... and, what happens to free radicals at higher pressures? Think about collision frequencies, kinetic theory of gases, mean free path ...

They're unstable at higher pressures?
 
zachem62 said:
it has 1 unpaired valence electron
What do unpaired electrons do?
 
Bystander said:
What do unpaired electrons do?
well, the atom with an unpaired electron would be highly reactive
 
zachem62 said:
well, the atom with an unpaired electron would be highly reactive

Why do you stop here? Try to draw conclusions from what you just wrote and from what Bystander wrote in the post #2.
 

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