Why Is (-i d/dx) Chosen as the Momentum Operator in Quantum Mechanics?

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SUMMARY

The momentum operator in quantum mechanics is defined as (-i d/dx) due to its Hermitian properties, leading to the canonical commutation relation [x,p]=ih. This choice ensures that the eigenvalue of the momentum operator corresponds to p, rather than -p. The discussion highlights that while both (-i d/dx) and (i d/dx) are mathematically valid, the convention adopted in quantum mechanics and Fourier series is critical for consistency in results, particularly in defining integrals such as f(x) = ∫ (d^3p/(2π)^3) f(p) e^{ipx}.

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Both (i d/dx) and (-i d/dx ) are Hermitian. For some reason (-i d/dx ) is chosen to be the momentum operator, and the consequences are that [x,p]=ih (and not -ih), and that e^{ipx} is an eigenvalue of momentum p (and not -p).

Is there any fundamental reason why [x,p] can't be -ih, and e^{ipx} can't have an eigenvalue -p, so that the momentum operator can be (i d/dx) ?

When dealing with Fourier series, f(x)=\int d^3p \mbox{ } f(p) e^{-ipx} would be incorrect, right? It would have to be f(x)=\int d^3p \mbox{ } f(p) e^{ipx} if you choose (-i d/dx )?

Do most math books use f(x)=\int d^3p \mbox{ } f(p) e^{-ipx} or f(x)=\int d^3p \mbox{ } f(p) e^{ipx} for their definition of a Fourier series? Which convention do you use for a Fourier series?
 
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There is no fundamental reason. In fact, all quantum mechanics (indeed, all mathematics) remains valid under the substitution, everywhere, of i -> -i. The reason is that there is some ambiguity in defining i in the first place. There are two square roots of -1, after all.

The convention I use for Fourier integrals is

f(x) = \int \frac{d^3p}{(2\pi)^3} \; f(p) e^{ipx}
 

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