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Why is it that cocaine crystals aren't transparent

  1. Dec 28, 2016 #1
    So I admittedly was a former cocaine user. I've since cleaned up and am back in school and my life is going in the right direction for once. I took a class in organic chemistry this previous semester and we did a lab on recrystallization. I think it was boric acid that I recrystallized, but I remember reading before that transparent crystals tend to be the purest.

    Anyway, one thing about cocaine is that when it is of very high quality (high purity), it is composed of pearly flakes which are not transparent at all. They look silverish, like aluminum. Very shiny. Why is it that cocaine crystals, when they're of high purity, aren't transparent but other crystals are? This seems counter-intuitive to me.

    [​IMG]
     
    Last edited by a moderator: Dec 28, 2016
  2. jcsd
  3. Dec 29, 2016 #2

    Bystander

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    ... and, your question is what? Physiological effects are unrelated to "purity/quality" as you seem to think. "Quality" does not imply purity.
     
  4. Dec 29, 2016 #3
    You seem to be saying that just because a user thinks the product is high quality, doesn't mean its purity is high. This may be correct, but drug seizures easily reach into the high 80%'s to lower 90%'s for purity, yet the product is still pearl flakes. This still leaves me asking, why aren't these high purity crystals transparent, like high purity crystals of other substances?

    EDIT: I'm actually looking at pictures right now of crystals of substances (like gemstones for example), which are pure, but aren't transparent. Am I incorrect in my assumption that a pure crystal must be a transparent one?
     
  5. Dec 29, 2016 #4

    Vanadium 50

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    Yes. Metals are composed of tiny crystals, for example.

    Also, while 90% may be 'high purity' to a junkie, it's not to a chemist. >99% is not uncommon.
     
  6. Dec 29, 2016 #5
  7. Dec 29, 2016 #6

    mfb

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    "High purity" in chemistry is more like 99.999%.

    Even with 100% purity, there are two things that can make the material intransparent:
    - the crystal itself can absorb or reflect visible light. Every metal is an example.
    - the material can be made out of many small crystals that are loosely connected. Light can be scattered at every border between those crystals, and the material looks white. Snow is an example: the individual ice crystals are transparent, but you have to many surfaces that scatter light that snow does not look clear. Compressed to solid ice with larger and more compact crystals it gets transparent again.
     
  8. Jan 5, 2017 #7
    Material also can include impurities with other refractive index.
     
  9. Jan 5, 2017 #8
    This brings to my mind something else that is expensive, namely gemstones. Rubies should be very clear and transparent when without any fractures in them, but almost always there are so called "inclusions", which are small fractures inside the stone and make it less transparent:

    [​IMG]

    Of course, the expensiveness of those gemstones can vary greatly depending on the clearness of their appearance. In the case of drugs, the appearance of the material doesn't usually matter much, though.
     
  10. Jan 6, 2017 #9
    You should try to recrystallize it and cool it very slowly.
     
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