Why is the active mass of solids taken as unity?

In summary, the active mass of solids is taken as unity in order to simplify calculations and facilitate direct comparisons between different substances. This does not mean that all solids have the same active mass, as it may vary depending on the substance. The active mass of solids is determined by dividing the mass of the substance by its molar mass and comparing it to the standard unit of one mole. However, there are exceptions to taking the active mass as unity, particularly when dealing with substances with low molar masses. Using the active mass of solids in scientific calculations allows for more accurate and standardized measurements, making comparisons between different substances easier.
  • #1
Dr.azwar
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Homework Statement


I understood the fact that since the density of solids and liquids remain constant in a reaction therefore the active mass must be a constant.But why is it that we take it as unity. Is is some kind of coonverntion,or is there a reason behind it?

Homework Equations

The Attempt at a Solution

 
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  • #2
Convention, with a good reason behind - 1 is a nice number that makes calculations easy.
 

1. Why is the active mass of solids taken as unity?

The active mass of solids is taken as unity because it simplifies calculations and makes them easier to understand. It also allows for a direct comparison of the active mass of different substances, as they are all measured relative to the same standard.

2. Does this mean that all solids have the same active mass?

No, the active mass of solids may vary depending on the substance. However, taking it as unity allows for a standardized comparison between different solids.

3. How is the active mass of solids determined?

The active mass of solids is determined by dividing the mass of the substance by its molar mass. This gives the number of moles of the substance present, which is then compared to the standard unit of one mole.

4. Are there any exceptions to taking the active mass of solids as unity?

Yes, in some cases, the active mass of solids may not be taken as unity. This is usually when dealing with substances that have a very low molar mass, as taking the active mass as unity may result in a value that is too small for practical use.

5. What is the significance of using the active mass of solids in scientific calculations?

Using the active mass of solids allows for more accurate and precise calculations in chemistry and other scientific fields. It also helps to standardize measurements and allows for easier comparisons between different substances.

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