Why is the Average Bond Enthalpy of O2 Different from its Formation Enthalpy?

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SUMMARY

The average bond enthalpy of O2 is 495 kJ/mol, while its formation enthalpy is defined as 0 kJ/mol. This discrepancy arises from the definitions of bond enthalpy and formation enthalpy. Bond enthalpy measures the energy required to break a bond in a molecule, while formation enthalpy refers to the energy change when one mole of a compound is formed from its elements in their standard states. Therefore, the two values represent different thermodynamic concepts and cannot be directly compared.

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  • Understanding of thermodynamic concepts such as bond enthalpy and formation enthalpy.
  • Familiarity with chemical bonding and molecular structure.
  • Knowledge of standard states of elements in thermodynamics.
  • Basic principles of energy changes in chemical reactions.
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daivinhtran
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why is average bond enthalpy of O2 is 495...But the formation enthalpy of O2 is 0 ??
Why are they different??
 
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See the definition of formation of Enthalpy.
 

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