Why is the diffusion coefficient in Fick's law squared?

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The discussion centers on Fick's first law of diffusion, specifically the units of the diffusion coefficient (D). The equation J_{x} = -D ∂φ/∂x describes the flux (J_{x}) of a substance, where D is in units of area/time. This is necessary because D quantifies the rate at which material diffuses through a surface area, thus requiring area dimensions in its units. The clarification provided by user jjmclell emphasizes that the inclusion of area in the diffusion coefficient is essential for accurately representing the physical process of diffusion.

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jjmclell
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Hi there,

I'm trying to wrap my head around Fick's first law of diffusion (for one dimension):

J_{x} = -D \frac{\partial \phi}{\partial x}

I understand that \phi is the concentration in units amount/volume and that x is position on the gradient in units length. What I don't understand is why -D is in units area/time. If we're talking one dimensional diffusion, why do we bring area into the equation? Or, put another way, why do we square length in the diffusion coefficient?

Thanks,

jjmclell
 
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It's in units of area/time because it represents the flux of material through a (control) surface
 

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