Start with the filled conducting solid. The stationary electric field inside any such conductor is zero because if it wasn't then that non-zero field would drive an electric current according to ##\vec J = \sigma \vec E##, where ##\sigma## is the conductance. In particular, this means that any charge on the conducting filled sphere is located on the surface because according to Gauss' law ##\rho \propto \nabla \cdot \vec E = 0## inside the conductor.
Now we know that any charge on the conducting filled sphere will arrange itself on the surface such that the internal field is zero. This charge configuration is also possible on the hollow sphere and will be the lowest energy configuration also in that case. Hence, also on the hollow sphere, the charge configuration on the surface will be such that the field inside is zero.