Why is the spin of hydrogen atom 1/2 in NMR spectroscopy?

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Homework Help Overview

The discussion revolves around the spin of the hydrogen atom in the context of NMR spectroscopy, specifically questioning why the hydrogen atom is described as having a spin of 1/2 despite its constituent particles, the electron and proton, both having spin 1/2.

Discussion Character

  • Conceptual clarification, Assumption checking

Approaches and Questions Raised

  • Participants explore the relationship between the spins of the electron and proton, questioning how these contribute to the overall spin of the hydrogen atom. Some participants reference external sources to clarify the concept of nuclear spin and its notation.

Discussion Status

The discussion is active, with participants providing clarifications and differing viewpoints on the role of electron and nuclear spins in determining the overall spin of hydrogen. There is no explicit consensus, but various interpretations and insights are being explored.

Contextual Notes

Participants note that the context of NMR spectroscopy specifically focuses on nuclear spin, suggesting that the electron's spin may not be relevant in this scenario. There are also references to the implications of spin in the context of Bose-Einstein condensates.

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if the electron has spin 1/2 and proton has spin 1/2, why is the hydrogen atom (which is made of the electron and proton) have spin of 1/2?
 
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It doesn't. Hydrogen can have a spin of either 0 or 1.

Assuming we mean the isotope whose nucleus has one proton and no neutrons.
 
Weird. I noticed it says Spin 1/2+. I don't know what the + is supposed to mean.
 
I believe that the 1/2+ is the nuclear spin and parity.
 
can you add electron and nuclear spin? I thought they were completely different.
 
When we talk about the spin of hydrogen, we are talking about the spin of the hydrogen nucleus (i.e. a proton). The electron doesn't figure into this.
 
Thanks for clarifying everybody.

FYI, when laser cooling is used to make Bose-Einstein condensates with atoms, the electron and nuclear spins both figure into determining whether the atom is a boson or fermion.
 
Ygggdrasil said:
When we talk about the spin of hydrogen, we are talking about the spin of the hydrogen nucleus (i.e. a proton). The electron doesn't figure into this.

you mean the other way around? electron spin matters since it's intrinsic magnetic moment is much greater than the hydrogen nucleus. this is because the proton mass >> electron mass
 
  • #10
Most of the time I've heard people discuss the spin of hydrogen is in the context of NMR spectroscopy, a technique that measures the energy differences between nuclear spin states in the presence of a magnetic field. For this technique, the spin of the electrons are not important.
 

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