Why the photoelectric absorption section finite at threshold

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SUMMARY

The discussion centers on the photoelectric effect of the hydrogen atom, specifically addressing the discrepancy between theoretical predictions and observed phenomena at the absorption threshold. According to the Fermi golden rule, the absorption rate should be proportional to the density of final states, which theoretically becomes zero at threshold due to the electron's zero momentum. However, the argument fails because exact zero momentum is not a valid state; finite transition times introduce a small momentum range, resulting in a non-zero absorption coefficient near the threshold.

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zweiling
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I mean the photoelectric effect of the hydrogen atom.

It is weird. By the Fermi golden rule, the transition or absorption rate is proportional to the density of the final states. At threshold, the electron has zero momentum and thus zero density of state. Therefore, the absorption coefficient should be zero at the threshold. Where does this argument go wrong?
 
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Exactly zero momentum is not a proper state. Every finite transition time gives a small momentum range.
 
mfb said:
Exactly zero momentum is not a proper state. Every finite transition time gives a small momentum range.
anyway, close to the threshold, the absorption section should be close to zero. But in reality, it is finite.
 

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