Will a Carbonate React with Carbonic Acid? A Chemical Reaction Explanation

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Discussion Overview

The discussion centers on whether a carbonate, specifically calcium carbonate, will react with carbonic acid. It explores the chemical interaction between these substances, touching on concepts of equilibrium and acidity.

Discussion Character

  • Technical explanation, Conceptual clarification

Main Points Raised

  • One participant questions if calcium carbonate will react with carbonic acid, presenting a chemical equation as a basis for the inquiry.
  • Another participant provides a link to external content related to the chemistry of carbonates.
  • A later reply asserts that carbonic acid does not exist in a free state and explains the equilibrium established when CO2 dissolves in water, suggesting that the concentration of hydrogen ions is insufficient to react with carbonate ions.
  • This participant further elaborates that for an acid-base reaction to occur, the acid must be sufficiently acidic, citing examples of other acids that do react with hydrogencarbonate.

Areas of Agreement / Disagreement

There is no consensus on whether a reaction occurs, as participants present differing views on the existence of carbonic acid and its reactivity with carbonates.

Contextual Notes

The discussion highlights assumptions about the state of carbonic acid and the conditions necessary for a reaction, which remain unresolved.

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hi i was wondering if a carbonate will react with carbonic acid. such as calcium carbonate with carbonic acid: CaCO3+H2CO3CaCO3+CO2+H2O. Thanks for the help!
 
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Thanks for the help! Borek!
 
Carbonic acid doesn't exist in the free state. When CO2 dissoves in water an equilibrium is set up between CO2 molecules (possibly solvated) and water on one hand and an aquated proton (a hygrogen ion) and the aquated hydrogencarbonate ion on the other. The concentration of hydrogen ions is too low to react with carbonate ions from the calcium carbonate so no reaction! Or in other words, the pH of "dissolved CO2" is not low enough to allow reaction with carbonate ions. In any acid-base reaction the acid must be acidic enough to react with the base which is why carboxylic acids (like acetic acid) react with hydrogencarbonate but phenols don't.
Hope this helps.
 

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