Will adding Ar(g) shift the equilibrium in 2NOCl(g) <--> 2NO(g) + Cl2(g)?

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SUMMARY

The discussion centers on the effect of adding Argon (Ar) gas to the equilibrium reaction 2NOCl(g) <--> 2NO(g) + Cl2(g), with a Gibbs free energy change (ΔG) of +77.1 kJ. It is established that adding Ar(g) at constant volume does not shift the equilibrium, as it does not affect the concentrations of the reactants or products. However, at constant pressure, the addition of Ar(g) can influence the system, potentially shifting the equilibrium. The inert nature of Argon is a key factor in this analysis.

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Homework Statement




For the equalibrium: 2NOCl(g)<-->2NO(g)+Cl2(g), delta G=+77.1kJ
Determine in which direction the equilibrium will shift by the following changes.

A) Ar(g) is added to the reaction

Homework Equations





The Attempt at a Solution



My first thought is that this will not alter the equilibrium as no change has been made to the individual parts of the chemical equation. I hope someone could point me in the right direction, if i am wrong or confirm that this is the right conclusion.

Thank you,
 
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Are there any other conditions given? Ie constant pressure/volume. Because Argon is an inert gas, and in one of the two conditions, nothing changes. The other one does.

Constant volume, nothing changes. Constant pressure, things will change.
 

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