Will All Metals Deposit on the Copper Cathode in My Electrolysis Experiment?

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Discussion Overview

The discussion revolves around the electrolysis of a pregnant leach solution containing metals such as copper, iron, and cobalt. Participants explore whether all these metals will deposit on a copper cathode when using a lead anode in the electrolysis setup.

Discussion Character

  • Exploratory, Technical explanation, Debate/contested

Main Points Raised

  • One participant inquires if all metals in the solution will deposit on the copper cathode during electrolysis.
  • Another participant suggests that while copper may deposit, the presence of hydrogen could prevent other metals from depositing.
  • A follow-up question seeks clarification on whether copper is the only metal that might deposit under the right conditions.
  • It is noted that electrorefining is used for copper purification, indicating that other metals may also deposit depending on their position in the reactivity series.
  • Some metals, like silver, may deposit if present in the solution, but this is contingent on their reactivity relative to hydrogen.

Areas of Agreement / Disagreement

Participants express differing views on whether all metals will deposit, with some agreeing that copper is likely to deposit while others highlight the influence of hydrogen and reactivity on the deposition of other metals.

Contextual Notes

The discussion does not resolve the specific conditions under which different metals would deposit, nor does it clarify the exact role of hydrogen in the process.

Who May Find This Useful

Individuals interested in electrolysis, metal deposition, or experimental chemistry may find this discussion relevant.

Ash1111
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Hi. I am a complete novice working on my first backyard experiment.

I have a 1part sulphuric acid 4parts tap water pregnant leach solution (from old copper mine tailings).

If I were to set up an electrolysis type experiment with a lead anode and a copper cathode should I expect all the metals (i.e. copper, iron, cobalt) in the solution to be deposited onto the cathode?

Thanks
 
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I don't think so. Copper, yes, but you have plenty of hydrogen to reduce before seeing these metals depositing.

Do you know what reactivity series is? While it is only approximate in many ways, it should give you a starting point.
 
Thanks Borek. Much appreciated!

Do you mean that copper is the only metal that might deposit in that experimental set up if the hydrogen count was right?
 
Ash1111 said:
Do you mean that copper is the only metal that might deposit in that experimental set up

Yes, that's why we use electrorefining for copper purification.

Note that some other metals (like silver) will deposit on the electrode as well (assuming it is present in the solution). It depends on where they are on the reactivity scale.
 

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