With which sample(s) of halide does sulphuric acid act as an oxidising agent?

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Discussion Overview

The discussion revolves around the behavior of concentrated sulphuric acid when added to solid samples of sodium chloride, sodium bromide, and sodium iodide, specifically focusing on which of these halides it acts as an oxidising agent. Participants explore the reactions and seek explanations for the observed outcomes.

Discussion Character

  • Exploratory
  • Technical explanation
  • Debate/contested

Main Points Raised

  • One participant suggests that concentrated sulphuric acid oxidises bromide (Br-) and iodide (I-) ions to bromine (Br2) and iodine (I2), proposing that the correct answer is C: sodium bromide and sodium iodide.
  • Another participant expresses confusion about how to approach the question, noting that their attempts to write equations for the reactions yield similar results, and they seek guidance on how to proceed.
  • A participant shares a link to a resource that may provide further information on the topic, indicating it as a helpful site for understanding halide ions and their reactions.

Areas of Agreement / Disagreement

There is no clear consensus on the explanation for the reactions, as participants express differing levels of understanding and seek clarification on the topic. Multiple viewpoints regarding the oxidising behavior of sulphuric acid with the halides are present.

Contextual Notes

Participants have not reached a resolution on the specific reactions or the reasoning behind the oxidising behavior of sulphuric acid with the halides. There are indications of uncertainty regarding the chemical equations and the nature of the reactions.

Who May Find This Useful

This discussion may be of interest to students or individuals studying chemistry, particularly those focusing on inorganic reactions involving halides and oxidising agents.

mutineer123
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Concentrated sulphuric acid is added to separate solid samples of sodium chloride, sodium
bromide or sodium iodide.
With which sample(s) does sulphuric acid act as an oxidising agent?
A sodium chloride only
B sodium chloride and sodium bromide
C sodium bromide and sodium iodide
D sodium iodide only

The answer is C. But what is the explanation? How do I approach questions like these, because I have no clue how to find the answer. I tried writing an equation for the 3 reaction, and they are all the same!
NaX + H2SO4 --> NaHSO4 + HX ( You can also use the Na2SO4 reaction) So what thread do I follow to crack this?
 
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It only oxidises Br- and I- to Br2 and I2 so C.) sodium bromide and sodium iodide should be the correct option
 
mutineer123 said:
Concentrated sulphuric acid is added to separate solid samples of sodium chloride, sodium
bromide or sodium iodide.
With which sample(s) does sulphuric acid act as an oxidising agent?
A sodium chloride only
B sodium chloride and sodium bromide
C sodium bromide and sodium iodide
D sodium iodide only

The answer is C. But what is the explanation? How do I approach questions like these, because I have no clue how to find the answer. I tried writing an equation for the 3 reaction, and they are all the same!
NaX + H2SO4 --> NaHSO4 + HX ( You can also use the Na2SO4 reaction) So what thread do I follow to crack this?

http://www.chemguide.co.uk/inorganic/group7/halideions.html
 

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