Your thoughts about the entropy of coal?

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    Coal Entropy Thoughts
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SUMMARY

The discussion focuses on the entropy of coal and its relationship to elemental composition, ash composition, and Low Heat Value (LHV). Participants emphasize that while enthalpy can be calculated from combustion data, the calculation of entropy requires additional information. The reference state for enthalpy is typically set at 273.15 K and 1 atm, with heats of formation commonly referenced at 298 K and 1 atm. The conversation highlights the need for clarity on the missing data necessary for accurate entropy calculations.

PREREQUISITES
  • Understanding of coal's elemental composition (C, H, O, N, S)
  • Knowledge of combustion processes and Low Heat Value (LHV)
  • Familiarity with thermodynamic concepts, specifically enthalpy and entropy
  • Awareness of standard reference states in thermodynamics (e.g., temperature and pressure conditions)
NEXT STEPS
  • Research the calculation methods for entropy in thermodynamics
  • Explore the significance of Low Heat Value (LHV) in fuel analysis
  • Study the relationship between elemental composition and thermodynamic properties of coal
  • Investigate standard reference states for enthalpy and entropy calculations
USEFUL FOR

Chemists, thermodynamic engineers, and professionals in the energy sector who are involved in fuel analysis and combustion processes will benefit from this discussion.

maajdl
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In the industry, coal and other fuels are typically represented by

- their C, H, O, N, S elemental composition for the combustible part​
- the composition of the ashes (SiO2, Al2O3, Fe2O3, ...)​
- the Low Heat Value (LHV) which is the heat that can be extracted from combustion product​

With these data, the "enthalpy" of coal can be calculated easily from the heat balance during combustion.

But what about the entropy of coal?
Do you think the entropy could be obtained on the basis of the same data listed here above.
Or is something missing? And how to fill the missing information then?

Just curiosity.

Thanks for your ideas ...

Michel
 
Science news on Phys.org
What reference state is used for the enthalpy of these substances (temperature, pressure)?
 
Usually T0=273.15 K , p0=1atm

Thanks for any suggestion

Michel
 
maajdl said:
Usually T0=273.15 K , p0=1atm

Thanks for any suggestion

Michel
Usually heats of formation are at 298 and 1 atm.
 

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