Your thoughts about the entropy of coal?

AI Thread Summary
The discussion focuses on the entropy of coal and whether it can be derived from its elemental composition, ash content, and Low Heat Value (LHV). Participants explore the relationship between these factors and the calculation of enthalpy during combustion, questioning if additional data is necessary for entropy assessment. The reference state for enthalpy calculations is typically set at a temperature of 273.15 K and a pressure of 1 atm, with heats of formation generally referenced at 298 K and 1 atm. The conversation highlights the complexities in accurately determining coal's entropy based on existing data. Overall, the inquiry emphasizes the need for clarity on the data required to assess entropy effectively.
maajdl
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In the industry, coal and other fuels are typically represented by

- their C, H, O, N, S elemental composition for the combustible part​
- the composition of the ashes (SiO2, Al2O3, Fe2O3, ...)​
- the Low Heat Value (LHV) which is the heat that can be extracted from combustion product​

With these data, the "enthalpy" of coal can be calculated easily from the heat balance during combustion.

But what about the entropy of coal?
Do you think the entropy could be obtained on the basis of the same data listed here above.
Or is something missing? And how to fill the missing information then?

Just curiosity.

Thanks for your ideas ...

Michel
 
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What reference state is used for the enthalpy of these substances (temperature, pressure)?
 
Usually T0=273.15 K , p0=1atm

Thanks for any suggestion

Michel
 
maajdl said:
Usually T0=273.15 K , p0=1atm

Thanks for any suggestion

Michel
Usually heats of formation are at 298 and 1 atm.
 
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