To achieve a boiling point of water at 20°C, the atmospheric pressure must be significantly reduced, with calculations suggesting around 25 mbar. The Clausius-Clapeyron equation is essential for determining this relationship, requiring basic algebra to apply correctly. It's important to note that the calculation assumes pure water, as impurities like salt increase the boiling point. Initial calculations led to confusion, indicating the need for careful arithmetic. Accurate resources like steam tables can provide reliable data for these calculations.