Sound waves cannot propagate as transverse waves in gases because gases lack resistance to shear forces, which are necessary for such wave propagation. In contrast, sound waves in solids can be transverse due to the tightly packed molecular structure that allows for vibrational movement along bonds. The discussion highlights the distinction between longitudinal waves, which are typical for gases, and the ability of solids to support both longitudinal and transverse waves. Understanding the molecular behavior in different states of matter is crucial to grasping why sound behaves differently in gases compared to solids. Overall, the properties of molecules and the nature of shear forces play a significant role in wave propagation.