- #1
Sekonda
- 207
- 0
Hey,
Given the fundamental thermodynamic relation (dN=0) ; TdS=pdV+dU, I have to argue that pdV is inexact. I know that dS and dU are exact differentials and that the integral of an exact differential around a closed loop will give a zero result, not too sure where to start, the question is only a couple of marks so the answer need only be brief but my understanding is limited as to why pdV, the work, has to be an inexact differential.
Any help appreciated!
Thanks.
Given the fundamental thermodynamic relation (dN=0) ; TdS=pdV+dU, I have to argue that pdV is inexact. I know that dS and dU are exact differentials and that the integral of an exact differential around a closed loop will give a zero result, not too sure where to start, the question is only a couple of marks so the answer need only be brief but my understanding is limited as to why pdV, the work, has to be an inexact differential.
Any help appreciated!
Thanks.