Exchanging roles of variable and thermal potential

In summary, in thermal physics, entropy is considered as a system variable in the 1st theorem of thermal dynamics, expressed as dE(S,V)=TdS-pdV=T(S,V)dS-p(S,V)dV. It is also regarded as a thermal potential, expressed as dS(E,V)=\frac{1}{T(E,V)}dE + \frac{p(E,V)}{T(E,V)}dV. The variables S,V,p,T are typically seen as variables, but the question is whether other variables such as V,p, and T can also be viewed as thermal potentials. This can only occur for the pair of E and S, as shown in the equations dV(S,E)=\frac{T
  • #1
sweet springs
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In thermal physics entropy S is regarded as a system variable in 1st theorem of thermal dynamics, i.e.
[tex]dE(S,V)=TdS-pdV=T(S,V)dS-p(S,V)dV[/tex]

Entropy is regarded also as thermal potential,i.e.

[tex]dS(E,V)=\frac{1}{T(E,V)}dE + \frac{p(E,V)}{T(E,V)}dV[/tex]

S,V,p,T are usually regarded as variables. My question is that other variables V, p, T can be also treated as thermal potentials ? Can exchanging roles of variable and thermal potential take place only for the pair of E and S ?
 
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  • #2
[tex]dV(S,E)=\frac{T(S,E)}{p(S,E)}dS-\frac{1}{p(S,E)}dE[/tex]
[tex]dT(F,V)=\frac{p(F,V)}{S(F,V)}dV-\frac{1}{S(F,V)}dF[/tex]
[tex]dp(G,T)=\frac{1}{V(G,T)}dG+\frac{S(G,T)}{V(G,T)}dT[/tex]
where
[tex]F=E-TS[/tex]
[tex]G=E-TS+PV[/tex]

V,T and p are thermal potential as S is. Is it OK?
 

Related to Exchanging roles of variable and thermal potential

1. What is the concept of exchanging roles of variable and thermal potential?

The concept of exchanging roles of variable and thermal potential refers to the phenomenon where the value of a variable is replaced by the thermal potential of a system. This allows for the analysis of a system in terms of its thermal properties rather than its individual variables.

2. How does exchanging roles of variable and thermal potential benefit scientific research?

Exchanging roles of variable and thermal potential can benefit scientific research by simplifying the analysis of complex systems. It allows for a more holistic understanding of a system's behavior and can also reveal new insights or relationships between variables and thermal properties.

3. What are some applications of exchanging roles of variable and thermal potential?

One application of exchanging roles of variable and thermal potential is in the study of phase transitions, such as melting or boiling, where the thermal potential plays a crucial role. It is also commonly used in the analysis of thermodynamic systems and can be applied to various fields such as materials science, chemistry, and engineering.

4. Are there any limitations to the concept of exchanging roles of variable and thermal potential?

While exchanging roles of variable and thermal potential can be a useful tool, it is not applicable to all systems. It is most commonly used for systems in thermal equilibrium and may not accurately represent the behavior of non-equilibrium systems. Additionally, it may not provide a complete understanding of a system and should be used in conjunction with other analytical methods.

5. How does exchanging roles of variable and thermal potential relate to the laws of thermodynamics?

The concept of exchanging roles of variable and thermal potential is closely related to the second law of thermodynamics, which states that the total entropy of a closed system will always increase over time. By analyzing a system in terms of its thermal potential, we can better understand how the system's entropy changes and how it obeys the laws of thermodynamics.

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