How Does Le Chatelier's Principle Affect Reactions in Chlorine Water Systems?

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In summary, the reversible reaction between Cl2(g) + H2O(l) = HCl(aq) + HClO(aq) can be affected by adding more HCl or NaOH, as it would shift the position of equilibrium and change the concentration of HClO and CIO^- ions. To remove the smell of chlorine gas, it would be best to consider alternatives rather than increasing its concentration. Mixing acid with bleach containing HCIO can be dangerous as it causes the reaction to proceed from right to left, releasing harmful gas.
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Physicsrapper
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Cl2(g) + H2O(l) = HCl(aq) + HClO(aq)
(reversible reaction)

1. What would happen to the concentration of HClO if more HCl was added?
Wouldn't it decrease, since the position of equilibrium then would shift to the left?

2. If NaOH was added to neutralize the acid, what would happen to the concentration of CIO^(-) (chlorate I) Ions?
Wouldn't it increase, since the position of equilibrium would shift to the right?

3. What would be the best way to remove the smell of chlorine gas?
Wouldn't it happen by increasing its concentration? Because then the Equilibrium would shift to the right an it's amount would decrease...

4. What would happen if acid was mixed with bleach containing HCIO? Why would that be dangerous?

Can someone please explain the answers?
 
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  • #2
1. yes
2.
3. We don't want more Cl gas smell, we want less. So consider alternatives.
4. The equation shows what happens. Reaction proceeds from the right to the left, liberating harmful gas.

(I'm leaving 2 for someone else to answer.)
 

What is Le Chatelier's principle?

Le Chatelier's principle, also known as the equilibrium law, states that when a system at equilibrium is subjected to a disturbance, it will adjust in such a way as to minimize the effect of the disturbance and maintain equilibrium.

How does Le Chatelier's principle apply to chemical reactions?

In chemical reactions, Le Chatelier's principle predicts that if a change is made to the concentration, pressure, or temperature of the reactants or products, the reaction will shift to counteract the change and maintain equilibrium.

What are the three factors that can affect equilibrium according to Le Chatelier's principle?

The three factors are concentration, pressure, and temperature. When any of these factors are changed, the equilibrium will shift to maintain equilibrium.

What happens to equilibrium if the concentration of a reactant is increased?

If the concentration of a reactant is increased, the reaction will shift to the right to consume the excess reactant and form more products. This will result in an increase in the concentration of the products and a decrease in the concentration of the reactants until a new equilibrium is reached.

How does temperature affect equilibrium according to Le Chatelier's principle?

An increase in temperature will favor the endothermic reaction (the reaction that absorbs heat) and shift the equilibrium to the right. Conversely, a decrease in temperature will favor the exothermic reaction (the reaction that releases heat) and shift the equilibrium to the left.

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