Understanding electronic configuration

  • #1
Chijioke
14
3
Homework Statement
How is electronic configuration an element shown?
Relevant Equations
Aufbau Principle
I don't really understand this electronic configuration of a thing. Suppose I want show the electronic configuration of calcium, how do I show it? Is like this
  1. 2, 8, 8, 2 or
  2. $$1s^22s^22p^63s^23p^64s^2$$
 
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  • #2
#2 is the winner!
 
  • #3
chemisttree said:
#2 is the winner!
What then do we call #1?
 
  • #4
I don't think it has a special name. Yes, it is a correct number of electrons on each shell, but it is filling of subshells that is much more important for chemical properties. That's why we prefer #2, as it tells as much more.

And yes, thanks to Aufbau principle they are to some degree equivalent.
 
  • #5
Borek said:
I don't think it has a special name. Yes, it is a correct number of electrons on each shell, but it is filling of subshells that is much more important for chemical properties. That's why we prefer #2, as it tells as much more.

And yes, thanks to Aufbau principle they are to some degree equivalent.
Why then is the filling of subshell much more important for chemical properties?
 
  • #6
You must represent it as in 2. for generality. The Madelung ordering principle has exceptions within the transition metals.
 
  • #7
Chijioke said:
Why then is the filling of subshell much more important for chemical properties?
Because it tells you which orbitals the valence electrons are in, and they are the most important electrons to understand things like the spectrum of atoms and chemical reactivity.
 
  • #8
Chijioke said:
Why then is the filling of subshell much more important for chemical properties?

In a way the only answer you can get is: because that's the way it is.

We don't create these rules, we observe reality and we try to understand and describe it. Sometimes we can - after creating a model of how something works - try to rationalize observed effects and rules and explain them in terms of for example energies involved, but it is not that these rationalizations are the "real" thing. The only real thing is - no pun intended - the observed reality.
 
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  • #9
Thatdburownnotationknownonly2u

That would be your own notation known only to you. We also have syntax rules for language and agreed upon spellings for words. It conveys better information in a clearer manner.
 
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What is electronic configuration?

Electronic configuration is the arrangement of electrons in an atom, molecule, or other physical structure. It describes the distribution of electrons in different energy levels, sublevels, and orbitals.

Why is understanding electronic configuration important?

Understanding electronic configuration is important because it helps us understand the chemical and physical properties of elements and compounds. It also allows us to predict how atoms will bond and interact with each other.

How is electronic configuration determined?

Electronic configuration is determined by the number of electrons in an atom and the rules of quantum mechanics. The Aufbau principle, Pauli exclusion principle, and Hund's rule are used to determine the specific arrangement of electrons in an atom.

What is the significance of the valence electrons in electronic configuration?

The valence electrons are the outermost electrons in an atom and are responsible for an element's chemical properties. They determine how an atom will bond with other atoms to form compounds.

How does electronic configuration change in different elements?

The electronic configuration of an element changes as the number of protons and electrons increase. This results in a change in the number of energy levels and sublevels, as well as the arrangement of electrons in orbitals. The pattern of electronic configuration can be seen in the periodic table of elements.

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