Vapor Pressure and Raoult's Law

In summary, the vapor pressure of a solution can be calculated by multiplying the mole fraction of the solvent by the vapor pressure of the pure solvent. In this case, the vapor pressure of the solution with 18g of sucrose added to 82g of water is 71.1 mm Hg. The mole fraction of water in the solution is 0.988, and the vapor pressure of pure water at 45 degrees C is 71.9 mm Hg. This approach is accurate and it is always recommended to double check work, especially when feeling tired.
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Homework Statement



The vapor pressure of pure water at 45 degrees C is 71.9 mm Hg. What is the vapor pressure when 18g of sucrose (MM = 342.3g/mol) is added to 82g of water?

Homework Equations



VP of solution = mole fraction of solvent * VP of pure solvent

The Attempt at a Solution



82g of water / (18g/mol) = 4.555... moles of water.

18g of sucrose / (342.3g/mol) = 0.0525 moles of water

Mole fraction of solvent (water) = 0.988.

0.988 * 71.9 mm Hg = new vapor pressure of 71.1 mm Hg.

Is my work correct? It's 3 AM here and I'm just a bit concerned about how accurate I am in doing these practice problems.
 
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I can confirm that your work is correct. The equation you used is the correct one for calculating the vapor pressure of a solution, and your calculations are accurate. It's always good to double check your work, especially when it's late at night and you're feeling tired. Keep up the good work!
 

1. What is vapor pressure?

Vapor pressure is the pressure exerted by the vapor of a substance in equilibrium with its liquid phase at a given temperature.

2. How is vapor pressure related to temperature?

Vapor pressure increases as temperature increases. This is because at higher temperatures, more molecules have enough energy to escape the liquid phase and become vapor.

3. What is Raoult's Law?

Raoult's Law states that the partial pressure of a component in a solution is equal to the vapor pressure of the pure component multiplied by its mole fraction in the solution.

4. How does Raoult's Law apply to real-life solutions?

Raoult's Law is an idealized equation and may not accurately describe real-life solutions. It assumes that the components in a solution have no interactions with each other and that their vapor pressures follow ideal gas behavior. In reality, there may be interactions between the components that affect their vapor pressures.

5. Can Raoult's Law be used for non-ideal solutions?

Raoult's Law can be used for non-ideal solutions if the deviations from ideal behavior are small. In these cases, the law can still provide a good estimate of the partial pressure of a component in a solution. However, for highly non-ideal solutions, other equations such as the Van't Hoff equation may be more accurate.

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