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  1. 5

    Internal energy or enthelpy are minimized in isoentropic processes?

    Now I think I have found it: Clausius inequality dS ≥ δq reversible/T I assumed that isoentropic process implied adiabatic irreversible process; however, it means that δq rev≤0 So I have that ΔS universe = ΔS system − ∫ ( δq rev /T ) > 0 If the process is isoentropic ΔS universe = − ∫ ( δq rev...
  2. 5

    Internal energy or enthelpy are minimized in isoentropic processes?

    Homework Statement How to demonstrate that U is minimized at constant V and S, while H at constant P and S? Homework Equations ΔS universe = ΔS system + ΔS environment ≥ 0 ΔU system = δq reversible + δw reversible = δq irreversible + δw irreversible ΔS environment = −∫(δq reversible / T) dU...
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