[b]1. You have a .246 M HNO3 solution. You also have 213mL of a 0.00666M 2,2' -bipyridine. You want a solution with pH 4.19. How man L of .246M HNO3 do you add to the 213mL other stuff?
[b]2. pH=pKa+log[A-]/[HA] also, pKa of 2,2' -bipyridine is 4.34 I think.
[b]3. pH=pKa+...