Yes and this is my proof:
Reflexive: x+x= 2.x and not 3.x so its not reflexive
Symmetric: x+y = 3k so y+x = 3k
Transitive: xRy and yRz
x+y=3k for keZ
x+y=3n for neZ
So x=3k-y and y=3n-y so x+z=3k-y+3n-y= 3(k+n)-2y We see that its not transitive
Because it hasnt al three properties it isn't an...