Thank you for the spherical cap formulae, but I think your algebra is wrong. Fixing the sphere radius R, and parameterizing the cap by h, I find the volume to be V=Pi h^2 (R - h/3) and the surface S=2 Pi R h. The lowest ratio is obtained when h=3R/2, and then V=9Pi/8 R^3, and S=3Pi R^2. Setting...