Let S on X be {(a,b), (a,c), (a,a), (b,a), (b,b), (c,a), (c,c)}. S is reflexive and symmetric, and S∘S= {(a,a), (a,b), (a,c), (b,b), (b,a), (b,c), (c,c), (c,a), (c,b)}
So S has 7 elements while S∘S has 9 elements, so S is reflexive and symmetric is not true.