Recent content by Twickel

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    Differences between para and ferroelectric materials

    Hi I am having toruble differentiating between the two. below the curie temperature BaTiO3 behaves as a ferroelectric, the Ti ions are offset from the centre, causing a polar domain. But it has a net polarisation is zero. Now above the curie temperature all the dipole cancel each other out...
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    Physical Chemistry- Using the integrated Vant Hoff Equation with K values.

    Thanks. I do not understand why I don't have to use the partial pressure, when it is in the expression for Kp. Is this the case for any equilibrium constant involving kp=[x]/Po2/atm?
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    Physical Chemistry- Using the integrated Vant Hoff Equation with K values.

    Homework Statement The equilibrium concentration of oxygen in fresh water exposed to the atmosphere is given for two temperatures. At 15 degrees celcius equilib [O2]= 630μmol/L at 25 degrees celcius equiln [O2]= 517μmol/L The expression for the equilibrium constant, K, between the oxygen...
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    Which Gas Has the Highest Vibrational Molar Heat Capacity at 50K?

    Thank you I figured out one and I just maked a low T approx for the second, so it is one. Q)The bond vibrational frequencies of F2, Li2, KCl and K2 are 274 x 1011 s-1, 105 x 1011 s-1, 84 x 1011 s-1 and 27 x 1011 s-1. Considering gases of the same low density of each species, which gas would...
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    Which Gas Has the Highest Vibrational Molar Heat Capacity at 50K?

    With regards to the rotational partition function, I narrowed it down to (1.5)^2/(1.1)^2 multiplied by e^(eob-eoa)/KbT, but I do not know the values of T so how do I complete this? Or is that actaully part of the ratio since its the ratio multiplied by e^(eob-eoa)/KbT You help is really really...
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    Which Gas Has the Highest Vibrational Molar Heat Capacity at 50K?

    Number 1 For the gas phase reaction, cyclopentene + I2 = cyclopentadiene + 2HI, we find that ln Kp = 7.55 - (4817K / T) (where the symbol K on the right hand side refers to the units Kelvin). What are the changes in entropy and enthalpy? Possible answers are ΔSo = 40.05 kJK-1mol-1 and...
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    Relationship between velocity and stopping distance

    Homework Statement Determines the relationship between velocity and stopping distance linking this to the force applied on the passenger or pedestrian, quantitatively. Homework Equations The Attempt at a Solution I have not found any so please provide relevant equations and...
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