Solving for temperature and volume of Dietrici Equation

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SUMMARY

The discussion focuses on solving for volume (v) and temperature (T) in the Dietrici Equation, represented as p = [RT/(v-b)]e^(a/vRT). The primary technique involves iterative methods, starting with the first-order approximation v = RT/p. Participants emphasize the use of Taylor series expansion for the exponential term and geometric series for simplifying the equation. This iterative approach allows for progressively accurate solutions for v by refining estimates based on higher-order terms.

PREREQUISITES
  • Understanding of the Dietrici Equation and its components
  • Familiarity with iterative solving techniques
  • Knowledge of Taylor series expansion
  • Basic principles of thermodynamics and gas laws
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  • Study iterative methods for solving nonlinear equations
  • Learn about Taylor series and their applications in physics
  • Explore geometric series and their convergence properties
  • Investigate the implications of the Dietrici Equation in real gas behavior
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Students and professionals in thermodynamics, chemical engineering, and applied mathematics who are interested in solving complex equations related to gas behavior and properties.

Riverbirdy
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Hi, guys! I came across hard stuff today. I really hope you can help a poor little worm like me. How do you solve for v & T correspondingly for equation like this⇒p = [RT/(v-b)]e^(a/vRT)?
What's the technique? How do you call it?
 
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The exponential can be expanded (Taylor series) ## e^x=1+x +x^2/2+... =1+x ## for small ## x ## . Normally, iterative techniques work well in solving this type of equation. To first order ## v=RT/p ##, etc. You take this ## v ## and write out the solution for ## v ## on the left with higher order terms on the right side of the equation. Then you get an improved answer for ## v ## and cycle it around again, etc. Also ## v-b=v(1-b/v) ## etc. The ## 1/(1-b/v) ## can stay on the right side and bring the ## v ## to the left...You can even write ##1/(1-b/v)=1+(b/v)+(b/v)^2+(b/v)^3+... ##. (i.e. a geometric series ## 1+r+r^2+r^3+...=1/(1-r)) ##.
 
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