Low Temperature Expansion of Chemical Potential

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SUMMARY

The discussion focuses on deriving a low temperature series expansion for the chemical potential of a weakly interacting Fermi gas using the Fermi-Dirac distribution function. Key equations include the Hartree-Fock approximation for the energy, the condition for particle density, and the derived expression for the chemical potential as a function of temperature. The final expression for the chemical potential includes terms dependent on the interaction potential and the Fermi wave vector, with a noted discrepancy in the calculation of the term G, which was found to provide a better approximation compared to previous results.

PREREQUISITES
  • Understanding of Fermi-Dirac statistics
  • Familiarity with the Hartree-Fock approximation
  • Knowledge of low temperature physics and series expansions
  • Basic concepts of quantum mechanics and particle density
NEXT STEPS
  • Study the derivation of the Fermi-Dirac distribution function in detail
  • Explore the Hartree-Fock approximation in the context of many-body physics
  • Research the Sommerfeld expansion method for non-interacting systems
  • Investigate numerical methods for calculating chemical potentials in interacting Fermi gases
USEFUL FOR

Physicists, particularly those specializing in condensed matter physics, quantum mechanics, and statistical mechanics, will benefit from this discussion, especially those working on Fermi gases and low temperature phenomena.

QuasiParticle
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I'm trying to derive a low temperature series expansion for the chemical potential of a weakly interacting Fermi gas. The starting point is, of course, the Fermi-Dirac distribution function (p is the particle momentum):

<br /> f(p) = \frac{1}{e^{\beta(\epsilon(p) - \mu)}+1} ,<br />

where, in the Hartree-Fock approximation, we have

<br /> \epsilon(p) = \frac{p^2}{2m} + n V(0) - \frac{1}{(2\pi \hbar)^3} \int d^3p&#039; V(\textbf{p} - \textbf{p}&#039; ) f(p&#039;).<br />

Here, m is the effective mass, n is the particle density, V(0) is the interaction potential V(q) at zero momentum transfer. The potential may be assumed to depend only on the momentum transfer V(\textbf{p} - \textbf{p}&#039; ) = V(| \textbf{p} - \textbf{p}&#039; | ) = V(q). The F-D distribution f(p&#039;) in the exchange term may be approximated with the non-interacting one. The chemical potential is determined by the condition (spin-1/2):

<br /> n = \frac{2}{(2\pi \hbar)^3} \int d^3p f(p) = \frac{1}{\pi^2 \hbar^3} \int_0^\infty p^2 f(p) dp<br />

Now, the right-hand side should somehow be expanded as a series in ( k_B T/ \mu)^2, which can then be inverted to give \mu as a function of T. It seems that the Sommerfeld method used for a non-interacting system is not easy to use in this case. I know the result should be the following:

<br /> \mu (T) = \mu_F (T) + n V(0) - \frac{1}{2} n \left[ F + G \frac{\pi^2}{12} \left( \frac{T}{T_F} \right)^2 \right] ,<br />

where
<br /> F = \frac{3}{2 k_F^3} \int_0^{2 k_F} k^2 \left( 1 - \frac{k}{2 k_F} \right) V(k) dk .<br />
and
<br /> G = 3 \left( V(2 k_F) - \frac{1}{4} \int_0^{2 k_F} \frac{k^3}{k_F^4} V(k) dk \right) .<br />

The potential is now written as a function of the Fermi wave vector (p = \hbar k). \mu_F (T) is the chemical potential of a non-interacting Fermi gas. The zero temperature limit, i.e. F, is rather simple to derive.

Has anyone come across this problem or know any good references? I would really appreciate any assistance.
 
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I guess I could update this thread a little bit. I was able to derive the requested expansion somewhat after posting the above message. My approach was, however, slightly different. The result also had an extra term and reads:

<br /> G = 3 \left( V(2 k_F) + \frac{1}{4} \int_0^{2 k_F} \left( \frac{k}{k_F^2} - \frac{3}{2} \frac{k^3}{k_F^4} \right) V(k) dk \right) .<br />

The reason for this small discrepancy is unclear. By comparing the two results to numerical calculations using the exact equations, I find that my G is a better approximation.
 

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