1D Quantum Well - I'm getting something very basic wrong

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SUMMARY

The discussion centers on calculating the number of energy levels in a 1D quantum well with a width of 5nm and a barrier height of 2eV. The relevant equation used is E_n = (n²π²ħ²)/(2mL²), with ħ = 6.582 × 10⁻¹⁶ eVs and m = 0.511 MeV. A participant initially miscalculated n² as approximately 1.9 due to unit inconsistencies but corrected it to 134 after realizing the need to maintain consistent units across energy, mass, and Planck's constant. The final correct calculation confirmed the expected result of 133 energy levels.

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  • Understanding of quantum mechanics, specifically 1D quantum wells
  • Familiarity with the equation E_n = (n²π²ħ²)/(2mL²)
  • Knowledge of unit conversions between electron volts and Joules
  • Basic proficiency in algebra for solving equations
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neural_jam
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Ok, so this example question is in my lecture notes:

Homework Statement



"For a 1-D quantum well, 5nm width, 2eV barrier height, calculate the number of energy levels in the well."

Homework Equations



So the equation given is a familiar one:

E_n=\frac{n^2 \pi^2 \hbar^2}{2 m L^2}

and he also said E_n=2 \times 1.6 \times 10^{-19} J

The Attempt at a Solution



Now, in the lecture n^2 came out to be 134, but I keep getting ~1.9, so I'm using the wrong units somewhere or something, because otherwise it's a pretty simple 'plug and chug' exercise..!

also, I'm using
\hbar = 6.582 \times 10^{-16} eVs
m = 0.511MeV

Can anyone help? :-s

-Jam
 
Last edited:
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Remember that the units of mass are

[m] = eV/c^2

And therefore with the values that you are using it should be

E_n=\frac{n^2 \pi^2 \hbar^2 c^2}{2 m L^2}
 
Hi, thanks for the reply!

Unfortunately, if I put in the factor of c^2, then n^2 becomes ~2.13^{-17}, even further off the 134 that it should be :-(
 
Make sure that you use the same units for everything. That is if you use electron volts as you said in your first post then E = 2 eV. If you use Joules for E then you have to use Js for h, kg for m (without c^2 this time) and so on.
 
I get 133, which seems pretty close... it's probably just a silly math mistake. If you write out the details of your calculations (and please be consistent with the units ;-), someone can probably pinpoint where it went wrong.
 
Ah, thankyou! Yes, it was a silly mistake, I forgot to change E=2 \times 1.6 \times 10^{-19} to E = 2, yes it works out fine now.

Thank you both, I have an exam tomorrow where this will likely be part of a question or two, so I'm very grateful for the help!
 

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