Time Dependent Wavefunction in Infinite Square Well

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Homework Help Overview

The problem involves a quantum particle of mass m confined in a one-dimensional infinite square well, defined between 0 and a. The initial wavefunction is specified for the left half of the well, and the task is to find the time-dependent wavefunction.

Discussion Character

  • Exploratory, Conceptual clarification, Mathematical reasoning

Approaches and Questions Raised

  • The original poster attempts to derive the time-dependent wavefunction using the expansion coefficients calculated from the initial wavefunction. Some participants question the validity of the approach and the implications of the coefficients for the right half of the well.

Discussion Status

Participants are engaged in clarifying the nature of the wavefunction and its evolution over time. There is recognition that the initial wavefunction is zero on the right side of the well, but discussions indicate that the wavefunction will not remain zero for all time. Some guidance is offered regarding the use of finite sums in computational tools.

Contextual Notes

There is an ongoing discussion about the implications of the initial conditions and the behavior of the wavefunction over time, particularly concerning the right half of the well. Participants are exploring the mathematical treatment of the problem without reaching a consensus on the interpretation of certain aspects.

wigglywinks
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Homework Statement


A particle of mass m is confined to a space 0<x<a in one dimension by infinitely high walls at x=0 and x=a. At t=0, the particle is initially in the left half of the well with a wavefunction given by,
$$\Psi(x,0)=\sqrt{\dfrac{2}{a}}$$
for 0<x<a/2

and,
$$\Psi(x,0)=0$$
for a/2 < x < a

Find the particle's time dependent wavefunction $$\Psi(x,t)$$

Homework Equations


I think the following equations are relevant (let me know if I don't have them written down correctly),
$$\Psi(x,t)=\sum_n^\infty c_n\psi_n(x) e^{-i E_n t/\hbar}$$
where $$\psi_n(x)=\sqrt{\dfrac{2}{a}}\sin\left(\dfrac{n\pi x}{a}\right)$$
and
$$E_n=\dfrac{n^2\hbar^2 \pi^2}{2ma}$$
and
$$c_n=\int_0^{a/2} \psi_n(x)\Psi(x,0)~dx$$

The Attempt at a Solution


I tried to find the time dependent wavefunction for the left half of the well. I'm not exactly sure what to do about the right half, but since the wavefunction at x=0 is equal to zero on the right half, the probabilities c_n would also be zero, so I'm thinking that the wavefunction is probably zero for the right half (so the full time dependent wavefunction for both halves would be piecewise continuous).

So for the left half of the well, I first tried to find c_n,

$$c_n=\int_0^{a/2}\sqrt{\dfrac{2}{a}}\sin\left(\dfrac{n\pi x}{a}\right)\sqrt{\dfrac{2}{a}}~dx$$
$$c_n=\frac{2}{a}\int_0^{a/2}\sin\left(\dfrac{n\pi x}{a}\right)~dx$$
so I get,
$$c_n=\dfrac{4\sin^2\left(\frac{n\pi}{4}\right)}{n\pi}$$

Then I plug this into

$$\Psi(x,t)=\sum_n^\infty c_n\psi_n(x) e^{-i E_n t/\hbar}$$
and also plugging in the equation for ψ_n(x), to get,
$$\Psi(x,t)=\sum_n^\infty \dfrac{4\sin^2\left(\frac{n\pi}{4}\right)}{n\pi}\sqrt{\dfrac{2}{a}}\sin\left(\dfrac{n\pi x}{a}\right) e^{-i E_n t/\hbar}$$

I tried to compute this on mathematica, but it didn't work (it looks like it probably diverges, but I don't know).

Does anyone know what I did wrong, or if this approach is even correct to begin with?
 
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When you wrote the expansion coefficients I think that you obtained ##c_n(t=0)##, if you use ##c_n## independent of ##t## then we speak of stationary solutions (or time independent solutions). Unless you are able to solve analitically the time dependent Schroedinger equation you can try to obtain ##c_n(t)## by plugging the series expansion of your wave function into Schroedinger equation with the initial value ##c_n(t=0)## which you calculated.
 
wigglywinks said:
Does anyone know what I did wrong, or if this approach is even correct to begin with?

You haven't done anything wrong.

With the coefficients you have calculated, the initial ##|\Psi(x,0)|^2## will be 0 on the right-hand side, but not for other values of t.
 
PeroK said:
With the coefficients you have calculated, the initial ##|\Psi(x,0)|^2## will be 0 on the right-hand side, but not for other values of t.
That's not correct. Did you plug in x=0 accidentally?
 
vela said:
That's not correct. Did you plug in x=0 accidentally?

The OP has the correct solution. Valid for ##0 < x < a##.

The wave function will evolve over time and be non-zero on the right-hand side.
 
Last edited:
It's not 0 for all x at t=0 either. That would imply the particle is nowhere.
 
I
vela said:
It's not 0 for all x at t=0 either. That would imply the particle is nowhere.
It's only 0 on the Right hand side, as per the definition of the initial function. It's constant probability on the left hand side.
 
Oh, I finally figured out what you mean. You mean 0 on the right half of the potential, not the righthand side of the equation.
 
wigglywinks said:
I tried to compute this on mathematica, but it didn't work (it looks like it probably diverges, but I don't know).
Did you try a finite sum of, say, 20 terms? Mathematica might choke on the infinite sum, but it has no problems calculating a partial sum.
 

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