2 moles of H20 heated at 10A for 1hr. What is the volume?

  • Context: Chemistry 
  • Thread starter Thread starter HelloCthulhu
  • Start date Start date
  • Tags Tags
    Moles Volume
Click For Summary
SUMMARY

The discussion centers on calculating the total volume of a system after electrolysis of 2 moles of water (H2O) at a current of 10A for 1 hour. Using Faraday's Law of Electrolysis, the participants derived that 3.358g of gas is produced, leading to a final volume of 32.65mL of water remaining after accounting for the gas produced. The conversation highlights the importance of knowing pressure and temperature to accurately determine the total volume of the system, which was not specified in the problem statement.

PREREQUISITES
  • Understanding of Faraday's Law of Electrolysis
  • Basic knowledge of gas laws and STP (Standard Temperature and Pressure)
  • Familiarity with chemical equations for electrolysis
  • Ability to perform calculations involving moles and gas volumes
NEXT STEPS
  • Study the principles of Faraday's Law of Electrolysis in detail
  • Learn about gas laws, particularly the Ideal Gas Law and its applications
  • Research the concept of Standard Temperature and Pressure (STP) and its significance in gas calculations
  • Explore the electrolysis process of different substances and their respective equations
USEFUL FOR

Chemistry students, educators, and anyone involved in electrolysis experiments or gas volume calculations will benefit from this discussion.

HelloCthulhu
Messages
150
Reaction score
3

Homework Statement


2 moles of water undergoes electrolysis at 10A. What is the total volume of the system after 1hr?

Homework Equations


4 H+(aq) + 4e−→ 2H2(g)

2 H2O(l) → O2(g) + 4 H+(aq) + 4e−

Faraday's Law of Electrolysis
Q = n(e-) x F

F = 96500C

The Attempt at a Solution



Initial volume = 36mL

Gas produced
(10*3600s*4g)/(F*4)=0.373g H2

(10*3600s*32g)/(F*4)=2.984g O2

0.373g+2.984g=3.358g

Final volume
36mL+3.35mL =39.358mL
 
Physics news on Phys.org
3.358 rounds up to 3.36
3.358g of gas does not make 3.358mL of gas.
If you start with 36g of H2O and you remove some of the H and some of the O you do not end up with 36g.
 
I apologize. I'm very new to chemistry. I thought I was solving for total volume including the expanding gas.

Final volume
36mL-3.35mL =32.65
 
You can't calculate total volume of "the system" not knowing the pressure and the temperature. Perhaps it is just a matter of lousy wording of the question, or you are expected to assume STP.

What you have found is the volume of water left. This is not total volume occupied.
 
Borek said:
You can't calculate total volume of "the system" not knowing the pressure and the temperature. Perhaps it is just a matter of lousy wording of the question, or you are expected to assume STP.

What you have found is the volume of water left. This is not total volume occupied.

Yes, it was very poor wording. Still new to writing these equations. Thank you for your help.
 

Similar threads

  • · Replies 3 ·
Replies
3
Views
3K
  • · Replies 26 ·
Replies
26
Views
5K
  • · Replies 3 ·
Replies
3
Views
6K
Replies
2
Views
2K
  • · Replies 9 ·
Replies
9
Views
3K
  • · Replies 4 ·
Replies
4
Views
2K
  • · Replies 2 ·
Replies
2
Views
5K
  • · Replies 1 ·
Replies
1
Views
5K
  • · Replies 7 ·
Replies
7
Views
7K
  • · Replies 1 ·
Replies
1
Views
4K