At those energies, you do not have a well-defined quark number of ##1##. Isn't that the point? When you collide protons at high energy it should not be physically impossible to get a free quark. But, because of the energy involved to split the proton there is always available energy to create enough quarks so that they group into mesons or baryons. Without colour confinement, just by luck you'd get a free quark every now and then.
So, yes, you can have a soup of ultra-high-energy quarks that do not stabilise into mesons and baryons. But, you cannot have just the one.
It's not as hard-and-fast as the PEP, perhaps, but without (low energy) colour confinement the theory falls apart.