A strange wave function of the Hydrogen atom

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SUMMARY

The discussion centers on the wave function of a hydrogen atom given by the equation ψ(r, θ, φ) = e^(i φ)e^(-(r/a)²(1 - μ cos² θ)), where a and μ are positive real parameters. The participants analyze the possible values for the measurement of L_z, concluding that the only possible measurement is ℏ due to m=1. They also explore the probability of measuring L² as 6ℏ², identifying that l must equal 2, leading to m values of ±1, ±2, and 0. The challenge lies in evaluating the coefficients of the eigenfunctions without complete decomposition of the wave function.

PREREQUISITES
  • Understanding of quantum mechanics, specifically angular momentum operators.
  • Familiarity with spherical coordinates in quantum wave functions.
  • Knowledge of hydrogen atom wave functions and their properties.
  • Ability to compute inner products of wave functions.
NEXT STEPS
  • Study the properties of angular momentum in quantum mechanics, focusing on L_z and L² measurements.
  • Learn how to compute inner products of quantum states, particularly for hydrogen atom wave functions.
  • Investigate the implications of parity in quantum states and how it affects wave function characteristics.
  • Explore the concept of linear combinations of stationary states in quantum mechanics.
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Students and professionals in quantum mechanics, particularly those studying atomic physics, wave functions, and angular momentum measurements in hydrogen atoms.

omegax241
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I am trying to solve the following exercise.

In a H atom the electron is in the state described by the wave function in spherical coordinates:

\psi (r, \theta, \phi) = e^{i \phi}e^{-(r/a)^2(1- \mu\ cos^2\ \theta)}

With a and \mu positive real parameters. Tell what are the possible values of the measurement of L_z, what is the probability that a measurement of L^2 gives the value 6 \hbar^2, and then what is the minimum value of an energy measurement.

First I've observed that m=1, so the only possible measurement for L_z is \hbar. (I'm pretty confident with this reasoning, but not so much.)For the other questions my idea was to rewrite the wavefunction as a linear combination of stationary states of the form \phi_{n,l,1}, but the problem is the square on the r part, and the fact that the angular part \theta is exponentiated.
In fact I've even started to ask myself is if necessary at all to find this decomposition to solve the problem, but nothing comes to mind.
Thank you for listening, every bit of help is appreciated.
 
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omegax241 said:
I am trying to solve the following exercise.

In a H atom the electron is in the state described by the wave function in spherical coordinates:

\psi (r, \theta, \phi) = e^{i \phi}e^{-(r/a)^2(1- \mu\ cos^2\ \theta)}

With a and \mu positive real parameters. Tell what are the possible values of the measurement of L_z, what is the probability that a measurement of L^2 gives the value 6 \hbar^2, and then what is the minimum value of an energy measurement.

First I've observed that m=1, so the only possible measurement for L_z is \hbar. (I'm pretty confident with this reasoning, but not so much.)For the other questions my idea was to rewrite the wavefunction as a linear combination of stationary states of the form \phi_{n,l,1}, but the problem is the square on the r part, and the fact that the angular part \theta is exponentiated.
In fact I've even started to ask myself is if necessary at all to find this decomposition to solve the problem, but nothing comes to mind.
Thank you for listening, every bit of help is appreciated.
To find the coefficient of a particular eigenfunction you do not need to completely decompose the wavefunction. Do you know how to do that?
 
omegax241 said:
Thank you for listening, every bit of help is appreciated.
I've had a look at this. I must admit I don't see how to tackle it. That wave function looks horrible. Sorry, I've no ideas either.
 
PeroK said:
To find the coefficient of a particular eigenfunction you do not need to completely decompose the wavefunction. Do you know how to do that?

Yes, I should evaluate the product:
\langle \phi_{n, l ,m} | \psi \rangle
But suppose I want to tackle the second question, if a value of 6 \hbar is found for L^2 this means that l = 2, and then m = \pm 1 ; \pm 2 ; 0. So I should evaluate the coefficents​
\langle \phi_{n, 2, \pm 1} | \psi \rangle
\langle \phi_{n, 2, \pm 2} | \psi \rangle
\langle \phi_{n, 2, 0} | \psi \rangle

But how can I find a definite number with this n dependence ?
 
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omegax241 said:
Yes, I should evaluate the product:
\langle \phi_{n, l ,m} | \psi \rangle
But suppose I want to tackle the second question, if a value of 6 \hbar is found for L^2 this means that l = 2, and then m = \pm 1 ; \pm 2 ; 0. So I should evaluate the coefficents​
\langle \phi_{n, 2, \pm 1} | \psi \rangle
\langle \phi_{n, 2, \pm 2} | \psi \rangle
\langle \phi_{n, 2, 0} | \psi \rangle

But how can I find a definite number with this n dependence ?
You know that ##m = 1##. It's the variable ##n## that's the problem.
 
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Doesn't parity tell you that an eigenstate of l=2 must be even? The wave function provided is odd.
 
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